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有机自组装低维圆偏振发光材料的研究进展

王梦竹 邓勇靖 刘淑娟 赵强

王梦竹, 邓勇靖, 刘淑娟, 赵强. 有机自组装低维圆偏振发光材料的研究进展[J]. 中国光学, 2021, 14(1): 66-76. doi: 10.37188/CO.2020-0192
引用本文: 王梦竹, 邓勇靖, 刘淑娟, 赵强. 有机自组装低维圆偏振发光材料的研究进展[J]. 中国光学, 2021, 14(1): 66-76. doi: 10.37188/CO.2020-0192
WANG Meng-Zhu, DENG Yong-Jing, LIU Shu-Juan, ZHAO Qiang. Research progress on organic self-assembling low-dimensional circularly polarized luminescent materials[J]. Chinese Optics, 2021, 14(1): 66-76. doi: 10.37188/CO.2020-0192
Citation: WANG Meng-Zhu, DENG Yong-Jing, LIU Shu-Juan, ZHAO Qiang. Research progress on organic self-assembling low-dimensional circularly polarized luminescent materials[J]. Chinese Optics, 2021, 14(1): 66-76. doi: 10.37188/CO.2020-0192

有机自组装低维圆偏振发光材料的研究进展

doi: 10.37188/CO.2020-0192
基金项目: 国家杰出青年科学基金(No. 61825503);国家自然科学基金(No. 61775101, No. 61805122)
详细信息
    作者简介:

    王梦竹(1990—),男,河南信阳人,博士研究生,2019年于温州大学获得硕士学位,主要从事有机圆偏振发光材料的研究。E-mail:18257753336@163.com

    赵强:赵 强(1978—),男,山东淄博人,教授,2007年于复旦大学获得博士学位,2010年8月晋升为南京邮电大学教授,主要从事有机与生物光电子学研究。E-mail:iamqzhao@njupt.edu.cn

  • 中图分类号: O6-1; O439

Research progress on organic self-assembling low-dimensional circularly polarized luminescent materials

Funds: Supported by National Funds for Distinguished Young Scientists (No. 61825503); National Natural Science Foundation of China (No. 61775101, No. 61805122)
More Information
  • 摘要: 具有圆偏振发光(CPL)性质的材料由于在3D显示、光学存储以及光学防伪等领域的重要应用,近年来越来越受到研究人员的关注。超分子策略能够将不同类型的分子组装成具有独特功能的低维(零维、一维和二维等)结构,因而成为构筑CPL活性有机低维材料的最有效方法之一。本文从超分子自组装驱动力的角度综述了近几年自组装CPL活性有机低维材料的研究进展。首先,本文系统地总结了现阶段设计自组装CPL活性有机低维材料的策略,其次重点讨论了这类材料的性能及应用,最后探讨了这一领域未来的发展机遇和挑战。
  • 图  1  多重氢键参与的共组装过程。(a)B-DNA结构中的多重氢键。(b)羧酸和吡啶类粘合剂之间的双重氢键能够形成手性纳米结构。(c)芳香族氨基酸和粘合剂的化学结构[25]

    Figure  1.  The co-assembly process with multiple hydrogen bonds. (a) Multiple hydrogen bonds in B-DNA structures. (b) The double hydrogen bond between carboxylic acids and pyridine-based binders can form chiral nanostructures. (c) The chemical structures of aromatic amino acids and binders[25]

    图  2  π-结构单元(GluCN)分别与硫黄素T(ThT)和羧酸氰基二苯乙烯衍生物(CAN)共组装示意图[30]

    Figure  2.  Illustration of the co-assembly of the π-structural unit (GluCN), thioflavin T (ThT) and carboxylic cyanostilbene derivative (CAN), respectively[30]

    图  3  手性稀土四面体笼的圆偏振发光和手性记忆效应[35]

    Figure  3.  Circularly polarized luminescence and chiral memory effect of chiral rare earth tetrahedral cage[35]

    图  4  手性MOF的CPL示意图[41]

    Figure  4.  Schematic illustration of CPL with chiral MOF[41]

    图  5  Cu14纳米团簇的合成及其手性特征[45]

    Figure  5.  Synthesis and chirality of Cu14 nanoclusters[45]

    图  6  钙钛矿纳米晶体手性示意图[48]

    Figure  6.  Illustration of the origin of chirality in perovskite nanocrystals[48]

    图  7  可能的自组装路线示意图[57]

    Figure  7.  Illustration of a possible self-assembly route[57]

    图  8  (a)对映体(S)-BPPOACZ和(R)-BPPOACZ的化学结构。(b)(R)-BPPOACZ的单晶结构。(c)(R)-BPPOACZ的HOMO和LUMO轨道分布示意图[61]

    Figure  8.  (a) Chemical structures of the enantiomers (S)-BPPOACZ and (R)-BPPOACZ. (b) Single crystal structure of (R)-BPPOACZ. (c) HOMO and LUMO orbital distributions of (R)-BPPOACZ[61].

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  • 收稿日期:  2020-10-23
  • 修回日期:  2020-11-30
  • 网络出版日期:  2021-01-14
  • 刊出日期:  2021-01-25

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