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印刷钙钛矿太阳能电池研究进展

秦昱 林珍华 常晶晶 郝跃

秦昱, 林珍华, 常晶晶, 郝跃. 印刷钙钛矿太阳能电池研究进展[J]. 中国光学, 2019, 12(5): 1015-1027. doi: 10.3788/CO.20191205.1015
引用本文: 秦昱, 林珍华, 常晶晶, 郝跃. 印刷钙钛矿太阳能电池研究进展[J]. 中国光学, 2019, 12(5): 1015-1027. doi: 10.3788/CO.20191205.1015
QIN Yu, LIN Zhen-hua, CHANG Jing-jing, HAO Yue. Research progress of printed perovskite solar cells[J]. Chinese Optics, 2019, 12(5): 1015-1027. doi: 10.3788/CO.20191205.1015
Citation: QIN Yu, LIN Zhen-hua, CHANG Jing-jing, HAO Yue. Research progress of printed perovskite solar cells[J]. Chinese Optics, 2019, 12(5): 1015-1027. doi: 10.3788/CO.20191205.1015

印刷钙钛矿太阳能电池研究进展

doi: 10.3788/CO.20191205.1015
基金项目: 

国家自然科学基金项目 61604119

国家自然科学基金项目 61704131

国家自然科学基金项目 61804111

详细信息
    作者简介:

    秦昱(1997-), 男, 河南南阳人, 硕士研究生, 2017年于西安电子科技大学获得学士学位, 主要从事钙钛矿太阳能电池方面的研究。E-mail:qinyu_ic@163.com

    常晶晶(1988-), 男, 河南三门峡人, 教授, 2010年6月于四川大学获得学士学位, 2014年于新加坡国立大学获得博士学位, 毕业后继续在新加坡国立大学从事博士后研究工作。2015年通过"华山学者"菁英人才计划加入西安电子科技大学微电子学院。2016年入选国家"青年千人"人才计划。主要研究方向:1.有机及氧化物晶体管的制备及应用。2.有机及钙钛矿太阳能电池的相关研究。3.柔性印刷电子器件的制备及应用。E-mail:jjingchang@xidian.edu.cn

  • 中图分类号: TK519

Research progress of printed perovskite solar cells

Funds: 

National Natural Science Foundation of China 61604119

National Natural Science Foundation of China 61704131

National Natural Science Foundation of China 61804111

More Information
  • 摘要: 钙钛矿材料不仅具有载流子扩散长度长、可调节带隙宽、光吸收效率大等优点,并且其原料储量十分丰富,沉积过程所需的形成能较低,制备工艺可兼容大面积制造技术。总之,低生产成本、高转换效率和宽应用领域等优点使钙钛矿太阳能电池可与硅基太阳能电池相媲美,在能源生产中优势十分明显。在现阶段的钙钛矿研究中,高稳定性和大制备面积是钙钛矿光伏技术的研究热点,也是亟待突破的难点。本文综述了近年来采用印刷技术制备钙钛矿太阳能电池的原料组成、工艺控制等方面的研究进展,简述并比较了各种印刷技术的优点与局限性。重点讨论了钙钛矿太阳能电池印刷制备时需要考虑的因素,并列举了对于改善钙钛矿太阳能电池薄膜性能不同制备方法的尝试,评价了对于提高器件稳定性及工业生产适用性所采取的一些策略。
  • 图  1  几种印刷制备方法

    Figure  1.  Several printing production methods

    图  2  界面层调控方法及结果

    Figure  2.  Regulation methods and results for interface layer

    图  3  添加剂工程调控方法及结果

    Figure  3.  Additive engineering regulation method and results

    图  4  活性层调控方法及结果

    Figure  4.  Active layer regulation method and results

    图  5  电极调控方法及结果

    Figure  5.  Electrode regulation method and results

    表  1  几种印刷制备钙钛矿太阳能电池方法比较

    Table  1.   Comparison of printed perovskite solar cells

    制备方法 适用辊对辊 可印刷图案 最新PCE
    刮涂法 19%[14]
    狭缝式涂布 18.3%[17]
    丝网印刷 12.8%[21]
    喷墨打印 12.9%[22]
    喷涂法 11%[27]
    下载: 导出CSV
  • [1] ZHANG J R, BAI D L, JIN ZH W, et al.. 3D-2D-0D interface profiling for record efficiency all-inorganic CsPbBrI2 perovskite solar cells with superior stability[J]. Advanced Energy Materials, 2018, 8(15):1703246. doi: 10.1002/aenm.201703246
    [2] KOJIMA A, TESHIMA K, SHIRAI Y, et al.. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. Journal of the American Chemical Society, 2009, 131(17):6050-6051. doi: 10.1021/ja809598r
    [3] EGGER D A, BERA A, CAHEN D, et al.. What remains unexplained about the properties of halide perovskites?[J]. Advanced Materials, 2018, 30(20):1800691. doi: 10.1002/adma.201800691
    [4] YANG W S, PARK B W, JUNG E H, et al.. Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells[J]. Science, 2017, 356(6345):1376-1379. doi: 10.1126/science.aan2301
    [5] YOSHIKAWA K, KAWASAKI H, YOSHIDA W, et al.. Silicon heterojunction solar cell with interdigitated back contacts for a photoconversion efficiency over 26%[J]. Nature Energy, 2017, 2(5):17032. doi: 10.1038/nenergy.2017.32
    [6] SANCHEZ S, XIAO H, PHUNG N, et al.. Flash infrared annealing for antisolvent-free highly efficient perovskite solar cells[J]. Advanced Energy Materials, 2018, 8(12):1702915. doi: 10.1002/aenm.201702915
    [7] WILLIAMS S T, RAJAGOPAL A, CHUEH C C, et al.. Current challenges and prospective research for upscaling hybrid perovskite photovoltaics[J]. The Journal of Physical Chemistry Letters, 2016, 7(5):811-819. doi: 10.1021/acs.jpclett.5b02651
    [8] ONO L K, PARK N G, ZHU K, et al.. Perovskite solar cells-towards commercialization[J]. ACS Energy Letters, 2017, 2(8):1749-1751. doi: 10.1021/acsenergylett.7b00517
    [9] WHITAKER J B, KIM D H, LARSON B W, et al.. Scalable slot-die coating of high performance perovskite solar cells[J]. Sustainable Energy & Fuels, 2018, 2(11):2442-2449. https://www.researchgate.net/publication/326808360_Scalable_Slot-die_Coating_of_High_Performance_Perovskite_Solar_Cells
    [10] LI ZH, KLEIN T R, KIM D H, et al.. Scalable fabrication of perovskite solar cells[J]. Nature Reviews Materials, 2018, 3(4):18017. doi: 10.1038/natrevmats.2018.17
    [11] CHEN H, YE F, TANG W T, et al.. A solvent-and vacuum-free route to large-area perovskite films for efficient solar modules[J]. Nature, 2017, 550(7674):92-95. doi: 10.1038/nature23877
    [12] HE M, LI B, CUI X, et al.. Meniscus-assisted solution printing of large-grained perovskite films for high-efficiency solar cells[J]. Nature Communications, 2017, 8:16045. doi: 10.1038/ncomms16045
    [13] KIM J H, WILLIAMS S T, CHO N, et al.. Enhanced environmental stability of planar heterojunction perovskite solar cells based on blade-coating[J]. Advanced Energy Materials, 2015, 5(4):1401229. doi: 10.1002/aenm.201401229
    [14] TANG SH, DENG Y H, ZHENG X P, et al.. Composition engineering in doctor-blading of perovskite solar cells[J]. Advanced Energy Materials, 2017, 7(18):1700302. doi: 10.1002/aenm.201700302
    [15] YANG M J, LI ZH, REESE M O, et al.. Perovskite ink with wide processing window for scalable high-efficiency solar cells[J]. Nature Energy, 2017, 2(5):17038. doi: 10.1038/nenergy.2017.38
    [16] RONG Y G, MING Y, JI W X, et al.. Toward industrial-scale production of perovskite solar cells:screen printing, slot-die coating, and emerging techniques[J]. The Journal of Physical Chemistry Letters, 2018, 9(10):2707-2713. doi: 10.1021/acs.jpclett.8b00912
    [17] KIM Y Y, PARK E Y, YANG T Y, et al.. Fast two-step deposition of perovskite via mediator extraction treatment for large-area, high-performance perovskite solar cells[J]. Journal of Materials Chemistry A, 2018, 6(26):12447-12454. doi: 10.1039/C8TA02868K
    [18] HWANG K, JUNG Y S, HEO Y J, et al.. Toward large scale roll-to-roll production of fully printed perovskite solar cells[J]. Advanced Materials, 2015, 27(7):1241-1247. doi: 10.1002/adma.201404598
    [19] ZUO CH T, SCULLY A D, VAK D, et al.. Self-assembled 2D perovskite layers for efficient printable solar cells[J]. Advanced Energy Materials, 2019, 9(4):1803258. doi: 10.1002/aenm.201803258
    [20] LI X, TSCHUMI M, HAN H W, et al.. Outdoor performance and stability under elevated temperatures and long-term light soaking of triple-layer mesoporous perovskite photovoltaics[J]. Energy Technology, 2015, 3(6):551-555. doi: 10.1002/ente.201500045
    [21] MEI A Y, LI X, LIU L F, et al.. A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability[J]. Science, 2014, 345(6194):295-298. doi: 10.1126/science.1254763
    [22] MATHIES F, EGGERS H, RICHARDS B S, et al.. Inkjet-printed triple cation perovskite solar cells[J]. ACS Applied Energy Materials, 2018, 1(5):1834-1839. doi: 10.1021/acsaem.8b00222
    [23] MATHIES F, ABZIEHER T, RUEDA D, et al.. Multipass inkjet printing of methylammonium lead iodide for planar perovskite solar cells(Conference Presentation)[J]. Proceedings of SPIE, 2016, 9942:994209. doi: 10.1117/12.2238163?SSO=1
    [24] WEI ZH H, CHEN H N, YAN K Y, et al.. Inkjet printing and instant chemical transformation of a CH3NH3PbI3/nanocarbon electrode and interface for planar perovskite solar cells[J]. Angewandte Chemie International Edition, 2014, 53(48):13239-13243. doi: 10.1002/anie.201408638
    [25] GAMLIEL S, DYMSHITS A, AHARON S, et al.. Micrometer sized perovskite crystals in planar hole conductor free solar cells[J]. The Journal of Physical Chemistry C, 2015, 119(34):19722-19728. doi: 10.1021/acs.jpcc.5b07554
    [26] RAMESH M, BOOPATHI K M, HUANG T Y, et al.. Using an airbrush pen for layer-by-layer growth of continuous perovskite thin films for hybrid solar cells[J]. ACS Applied Materials & Interfaces, 2015, 7(4):2359-2366. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b2cdbd0815bae6c80fe95f113f44d3e3
    [27] BARROWS A T, PEARSON A J, KWAK C K, et al.. Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition[J]. Energy & Environmental Science, 2014, 7(9):2944-2950. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=0dcfc504ae06035b04e399af189270b4
    [28] HUANG H B, SHI J J, ZHU L F, et al.. Two-step ultrasonic spray deposition of CH3NH3PbI3 for efficient and large-area perovskite solar cell[J]. Nano Energy, 2016, 27:352-358. doi: 10.1016/j.nanoen.2016.07.026
    [29] CHANDRASEKHAR P S, KUMAR N, KUMAR SWAMI S, et al.. Fabrication of perovskite films using an electrostatic assisted spray technique:the effect of the electric field on morphology, crystallinity and solar cell performance[J]. Nanoscale, 2016, 8(12):6792-6800. doi: 10.1039/C5NR08350H
    [30] ISHIHARA H, SARANG S, CHEN Y C, et al.. Nature inspiring processing route toward high throughput production of perovskite photovoltaics[J]. Journal of Materials Chemistry A, 2016, 4(18):6989-6997. doi: 10.1039/C5TA09992G
    [31] HONG S C, LEE G, HA K, et al.. Precise morphology control and continuous fabrication of perovskite solar cells using droplet-controllable electrospray coating system[J]. ACS Applied Materials & Interfaces, 2017, 9(9):7879-7884. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=177dd60c38729f729547756b3b26a806
    [32] MOHAMAD D K, GRIFFIN J, BRACHER C, et al.. Spray-cast multilayer organometal perovskite solar cells fabricated in air[J]. Advanced Energy Materials, 2016, 6(22):1600994. doi: 10.1002/aenm.201600994
    [33] QIU L B, ONO L K, QI Y B. Advances and challenges to the commercialization of organic-inorganic halide perovskite solar cell technology[J]. Materials Today Energy, 2018, 7:169-189. doi: 10.1016/j.mtener.2017.09.008
    [34] WU W Q, WANG Q, FANG Y J, et al.. Molecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells[J]. Nature Communications, 2018, 9(1):1625. doi: 10.1038/s41467-018-04028-8
    [35] CHO A N, PARK N G. Impact of interfacial layers in perovskite solar cells[J]. ChemSusChem, 2017, 10(19):3687-3704. doi: 10.1002/cssc.201701095
    [36] YANG ZH B, CHUEH C C, ZUO F, et al.. High-performance fully printable perovskite solar cells via blade-coating technique under the ambient condition[J]. Advanced Energy Materials, 2015, 5(13):1500328. doi: 10.1002/aenm.201500328
    [37] BACK H, KIM J, KIM G, et al.. Interfacial modification of hole transport layers for efficient large-area perovskite solar cells achieved via blade-coating[J]. Solar Energy Materials and Solar Cells, 2016, 144:309-315. doi: 10.1016/j.solmat.2015.09.018
    [38] ZHANG Y M, ZHAO J H, ZHANG J, et al.. Interface engineering based on liquid metal for compact-layer-free, fully printable mesoscopic perovskite solar cells[J]. ACS Applied Materials & Interfaces, 2018, 10(18):15616-15623. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=925cd7c8aa3687d801ffa57978e42266
    [39] LI SH G, JIANG K J, SU M J, et al.. Inkjet printing of CH3NH3PbI3 on a mesoscopic TiO2 film for highly efficient perovskite solar cells[J]. Journal of Materials Chemistry A, 2015, 3(17):9092-9097. doi: 10.1039/C4TA05675B
    [40] PARK S M, NOH Y J, JIN S H, et al.. Efficient planar heterojunction perovskite solar cells fabricated via roller-coating[J]. Solar Energy Materials and Solar Cells, 2016, 155:14-19. doi: 10.1016/j.solmat.2016.04.059
    [41] LEE D, JUNG Y S, HEO Y J, et al.. Slot-die coated perovskite films using mixed lead precursors for highly reproducible and large-area solar cells[J]. ACS Applied Materials & Interfaces, 2018, 10(18):16133-16139. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b259cfb798c34cfd70d17a2df87cf1f4
    [42] PENG Y Y, CHENG Y D, WANG CH H, et al.. Fully doctor-bladed planar heterojunction perovskite solar cells under ambient condition[J]. Organic Electronics, 2018, 58:153-158. doi: 10.1016/j.orgel.2018.04.020
    [43] DENG Y H, PENG E, SHAO Y CH, et al.. Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers[J]. Energy & Environmental Science, 2015, 8(5):1544-1550. http://cn.bing.com/academic/profile?id=46a41ed2eacdea88cfebc21ee462f520&encoded=0&v=paper_preview&mkt=zh-cn
    [44] RAZZA S, DI GIACOMO F, MATTEOCCI F, et al.. Perovskite solar cells and large area modules(100 cm2) based on an air flow-assisted PbI2 blade coating deposition process[J]. Journal of Power Sources, 2015, 277:286-291. doi: 10.1016/j.jpowsour.2014.12.008
    [45] DENG Y H, WANG Q, YUAN Y B, et al.. Vividly colorful hybrid perovskite solar cells by doctor-blade coating with perovskite photonic nanostructures[J]. Materials Horizons, 2015, 2(6):578-583. doi: 10.1039/C5MH00126A
    [46] JEONG B, HWANG I, CHO S H, et al.. Solvent-assisted gel printing for micropatterning thin organic-inorganic hybrid perovskite films[J]. ACS Nano, 2016, 10(9):9026-9035. doi: 10.1021/acsnano.6b05478
    [47] HU Q, WU H, SUN J, et al.. Large-area perovskite nanowire arrays fabricated by large-scale roll-to-roll micro-gravure printing and doctor blading[J]. Nanoscale, 2016, 8(9):5350-5357. doi: 10.1039/C5NR08277C
    [48] MA Y CH, LEE J, LIU Y L, et al.. Synchronized-pressing fabrication of cost-efficient crystalline perovskite solar cells via intermediate engineering[J]. Nanoscale, 2018, 10(20):9628-9633. doi: 10.1039/C8NR01717D
    [49] ZHONG Y F, MUNIR R, LI J B, et al.. Blade-coated hybrid perovskite solar cells with efficiency >17%:an in situ investigation[J]. ACS Energy Letters, 2018, 3(5):1078-1085. doi: 10.1021/acsenergylett.8b00428
    [50] SCHMIDT T M, LARSEN-OLSEN T T, CARLō J E, et al.. Upscaling of perovskite solar cells:fully ambient roll processing of flexible perovskite solar cells with printed back electrodes[J]. Advanced Energy Materials, 2015, 5(15):1500569. doi: 10.1002/aenm.201500569
    [51] BINEK A, PETRUS M L, HUBER N, et al.. Recycling perovskite solar cells to avoid lead waste[J]. ACS Applied Materials & Interfaces, 2016, 8(20):12881-12886. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b30f085b04da2b064a475a6221f5a649
    [52] NOEL N K, ABISREUTINGER S N, WENGER B, et al.. A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films[J]. Energy & Environmental Science, 2017, 10(1):145-152. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=012f1d503d2231a72cce5d073eb0c45f
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出版历程
  • 收稿日期:  2019-01-29
  • 修回日期:  2019-03-03
  • 刊出日期:  2019-10-01

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