Volume 3 Issue 4
Sep.  2010
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HUA Jing-tian, CHEN Bao-jiu, SUN Jia-shi, CHENG Li-hong, ZHONG Hai-yang. Introduction to up-conversion luminescence of rare earth doped materials[J]. Chinese Optics, 2010, 3(4): 301-309.
Citation: HUA Jing-tian, CHEN Bao-jiu, SUN Jia-shi, CHENG Li-hong, ZHONG Hai-yang. Introduction to up-conversion luminescence of rare earth doped materials[J]. Chinese Optics, 2010, 3(4): 301-309.

Introduction to up-conversion luminescence of rare earth doped materials

  • Received Date: 11 Mar 2010
  • Rev Recd Date: 13 May 2010
  • Publish Date: 25 Aug 2010
  • Up-conversion luminescence in rare earth doped materials is an important approach for the optical frequency conversion as well an important aspect in the researches of luminescent materials. On the basis of the introduction of fundamental concepts of the up-conversion luminescence, the research history of up-conversion luminescence of rare earth doped materials was briefly reviewed and the up-conversion mechanisms including energy transfer, excited state absorption, co-operative sensitization, co-operative luminescence, two-photon absorbed excitation and photon avalanche processes in rare earth doped materials were summarized and compared with each others. Then, the up-conversion luminescence mechanisms for various rare earths doped materials were summarized and the host materials such as phosphors, crystal and non-crystalline solids for rare earth were introduced. Finally, the factors influencing the up-conversion luminescence efficiency were analyzed. It was pointed out that the absorptions of pumping light and emitting light, phonon energies of host materials, the choices of doping ions and pumping routes must be considered in the designs of up-conversion luminescence materials.

     

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  • [1] 陈宝玖. 稀土离子掺杂的玻璃材料制备及上转换发光 . 长春:中国科学院长春光学精密机械与物理研究所 ,1999. CHEN B J. Preparation and upconversion luminescence of rare earth doped glasses . Changchun:Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,1999.(in Chinese)

    [2] 孟庆裕. 纳米颗粒表面效应和尺寸限制对稀土离子发光的影响 . 长春:中国科学院长春光学精密机械与物理研究所 ,2007. MENG Q Y. Effects of surface and size-confinement on the rare earth luminescence . Changchun:Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,2007.(in Chinese)

    [3] 王博. 三价铒离子在ZBLAN中光学跃迁的研究 . 大连:大连海事大学 ,2008. WANG B. Optical transitions of trivalent erbium in ZBLAN . Dalian:Dalian Maritime University,2008.(in Chinese)

    [4] 徐东勇,臧竞存. 上转换激光和上转换发光材料的研究进展
    [J]. 人工晶体学报 ,2001,30(2):203-210. XU D Y,ZANG J C. Progress of study on upconversion laser & luminescence materials
    [J]. J. Synthetic Cryst.,2001,30(2):203-210.(in Chinese)

    [5] 陈晓波,张光寅,宋增福. 稀土化合物材料上转换发光与激光的研究与进展
    [J]. 光谱学与光谱分析 ,1995,15(3):1-6. CHEN X B,ZHANG G Y. SONG Z F. Progress in upconversion laser and luminescence of rare earths doped compounds
    [J]. Spectroscopy Spec. Anal.,1995,15(3):1-6. (in Chinese)

    [6] 杨建虎,戴世勋,姜中宏. 稀土离子的上转换发光及研究进展
    [J]. 物理学进展 ,2003,23(3):284-298. YANG J H,DAI SH X,JIANG ZH H. Upconversion emission of rare earth ions and its recent developments
    [J]. Prog. Phys.,2003,23(3):284-298.(in Chinese)

    [7] LIU M,WANG S W,ZHANG J,et al.. Upconversion luminescence of Y3Al5O12(YAG)∶ Yb3+,Tm3+ nanocrystals
    [J]. Opt. Mater.,2007,30(7):370-374.

    [8] GOUVEIA-NETO A S,BUENO L A,AFONSO A C M,et al.. Upconversion Luminescence in Ho3+/Yb3+ and Tb3+/Yb3+ codoped fluorogermanate glass and glass ceramic
    [J]. J. Non-Cryst. Solids,2008,354(10):509-514.

    [9] IPARRAGUIRRE I,AZKARGORTA J,FERNANDEZ-NAVARRO J M,et al.. Laser action and upconversion of Nd3+ in tellurite bulk glass
    [J]. J. Non-Cryst. Solids,2007,353(2):990-992.

    [10] ZHANG X D,XU T F,DAI S X,et al.. Investigation of energy transfer and frequency upconversion in Er3+/Ho3+ co-doped tellurite glasses
    [J]. J. Alloy. Compd.,2008,450(10):306-309.

    [11] 陈宝玖,王海宇,秦伟平,等. Yb3+和Er3+共掺杂氟硼酸盐玻璃材料光学跃迁及红外到可见上转换
    [J]. 发光学报 ,2000,21(1):38-42. CHEN B J,WANG H Y,QIN W P,et al.. Optical transitions and IR to visible upconversion of Yb3+ and Er3+ co-doped fluoroborate glass
    [J]. Chin. J. Lumin.,2000,21(1):38-42.(in Chinese)

    [12] 陈宝玖,王海宇,秦伟平,等. 高效的红外到可见上转换氟氧化物玻璃材料
    [J]. 光谱学与光谱分析 ,2000,20(3):257-259. CHEN B J,WANG H Y,QIN W P,et al.. Oxyfluoride glass for high efficient upconversion from IR to green
    [J]. Spectroscopy Spectral Anal.,2000,20(3):257-259.(in Chinese)

    [13] 杨艳民. 稀土离子掺杂透明无机绝缘体材料红外光谱性质的研究 . 长春:中国科学院长春光学精密机械与物理研究所 ,2007. YANG Y M. Investigation of infrared spectroscopic properties in rare earth ions doped insulating inorganic materials . Changchun:Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,2007.(in Chinese)

    [14] LIU M,WANG S W,ZHANG J,et al.. Dominant red emission (4F9/2-4I15/2) via upconversion in YAG(Y3Al5O12)∶Yb3+,Er3+ nanopowders
    [J]. Opt. Mater.,2007,29(3):1352-1357.

    [15] DUAN Z C,ZHANG J J,XIANG W D,et al.. Multicolor upconversion of Er3+/Tm3+/Yb3+ doped oxyfluoride glass ceramics
    [J]. Mater. Lett.,2007,61(9):2200-2203.

    [16] NICOLAS S,DESCROIX E,JOUBERT M F,et al.. Potentiality of Pr3+ and Pr3+/Ce3+ doped crystals for tunable UV upconversion lasers
    [J]. Opt. Mater.,2003,22(2):139-146.

    [17] GERNER P,FUHRER C,REINHARD C,et al.. Near infrared to visible photon upconversion in Mn2+ and Yb3+ containing materials
    [J]. J. Alloys Compd.,2004,380(1):39-44.

    [18] MARTIN I R,GOUTAUDIER C,GUY S,et al.. Room-temperature photon avalanche upconversion in Tm3+∶ Y2O3 crystals
    [J]. Phys. Rev. B,1999,60(10):7252-7257.

    [19] LOZANO W B,ARAUJO C B,MESSADDEQ Y,et al.. Enhanced frequency upconversion in Er3+ doped fluoroindate glass due to energy transfer from Tm3+
    [J]. J. Non-Cryst. Solids,2002,11(7):318-322.

    [20] GIRI N K,RAI D K,RAI S B. White light upconversion emissions from Tm3++Ho3++Yb3+ codoped tellurite and germanate glasses on excitation with 798 nm radiation
    [J]. J. Appl. Phys.,2008,104(12):113107/1-113107/5.

    [21] GIRI N K,SINGH A K,RAI S B. Efficient blue upconversion emission in Tm3+ via energy transfer from Yb3+ doped in lithium modified tellurite glass
    [J]. J. Appl. Phys.,2007,101(2):033102/1-033102/4.

    [22] QUIMBY R S,CONDON N J,OCONNOR S P,et al.. Upconversion and excited-state absorption in the lower levels of Er∶ KPb2Cl5
    [J]. Opt. Mater.,2008,30(3):827-834.

    [23] BOUFFARD M,DUVAUT T,JOUART J P,et al.. Site-selective upconversion excitation of Er3+∶ KYF4
    [J]. J. Phys.:Condens. Mater.,1999,11(3):4775-4782.

    [24] RAKOV N,ARAUJO C B,MESSADDEQ Y,et al.. Avalanche upconversion in Er3+ doped fluoroindate glass
    [J]. Appl. Phys. Lett.,1997,70(23):3084-3086.

    [25] KNOWLES D S,JENSSEN H P. Upconversion versus Pr-deactivation for efficient 3 μm laser operation in Er
    [J]. IEEE J. Quat. Electron.,1992,28(4):1197-1208.

    [26] ZHONG H Y,CHEN B J,REN G Z,et al.. 2.7 μm emission of Nd3+,Er3+ codoped tellurite glass
    [J]. J. Appl. Phys.,2009,106(1) in press.

    [27] WANG D Y,LUO J L,CHAO X B,et al.. Upconversion fluorescence in LiKGdF5 single crystal co-doped with Er3+,Tb3+
    [J]. SPIE,2006,6028:602807/1-602807/5.

    [28] WANG D Y,LUO J L,LIU J Q,et al.. Energy transfer upconversion in Er3+ doped and Er3+,Ho3+ codoped Cs2NaGdCl6 crystals
    [J]. SPIE,2005,6028:60280S/1-60280S/5.

    [29] LAHOZ F,MARTIN I R,BRIONES A. Infrared-laser induced photon avalanche upconversion in Ho3+-Yb3+ codoped fluoroindate glasses
    [J]. J. Appl. Phys.,2004,95(6):2957-2962.

    [30] W ANG X Y,LIN H,YANG D L,et al.. Optical transitions and upconversion fluorescence in Ho3+/Yb3+ doped bismuth tellurite glasses
    [J]. J. Appl. Phys.,2007,101(6):113535/1-113535/5.

    [31] YANG H G,DAI Z W, LI J F,et al.. Energy transfer and frequency upconversion in Pr3+-doped ZBLAN glass
    [J]. J. Non-Cryst. Solids,2006,352(9):5469-5474.

    [32] GOMES A S L,MACIEL G S,ARAUJO R E,et al.. Diode pumped avalanche upconversion in Pr3+ doped fibers
    [J]. Opt. Commun.,1993,103(5-6):361-364.

    [33] EDISON F F L,ARAUJO C B,MESSADDEQ Y. Frequency upconversion involving triads and quartets of ions in a Pr3+/Nd3+ codoped fluoroindate glass
    [J]. J. Appl. Phys.,2001,92(6):3065-3070.

    [34] BANEY D M,RANKIN G,CHANG K W. Simultaneous blue and green upconversion lasing in a laser-diode-pumped Pr3+/Yb3+ doped fluoride fiber laser
    [J]. Appl. Phys. Lett.,1996,69(12):1662-1664.

    [35] IPARRAGUIRRE I,AZKARGORTA J,FERNANDEZ-NAVARRO J M,et al.. Laser action and upconversion of Nd3+ in tellurite bulk glass
    [J]. J. Non-Crystal. Solids,353(2):990-992.

    [36] QIU J. Energy transfer process and Tb3+ up-conversion luminescence in Nd3+/Yb3+/Tb3+ co-doped fluorozirconate glasses
    [J]. J. Lumin.,2000,86(1):23-31.

    [37] QIU J,SHOJIYA M,KANNO R,et al.. Selectively strong green up-conversion luminescence in Nd3+-Ho3+ co-doped ZrF4 based fluoride glasses under 800 nm excitation
    [J]. J. Phys.:Condens. Matter.,1998,10(12):11095-11102.

    [38] WANG X F,BU Y Y,XIAO S G,et al.. Novel upconversion phenomenon of Nd3+ sensitized by Yb3+ in Nd3+-Yb3+ codoped a-Na(Y1.5Na0.5)F6
    [J]. Mater. Lett.,2008,62(23):3865-3867.

    [39] MA H P,ZHU B G,ZOU F L,et al..Three-photon-excited fluorescence of Tb3+-doped CaO-Al2O3-SiO2 glass by femtosecond laser irradiation
    [J]. J. Rare Earths,2008,26(6):928-931.

    [40] NOGINOV M A,VENKATESWARLU P,MAHADI M. Two-step upconversion luminescence in Yb∶ Tb∶ YSGG Crystals
    [J]. J. Opt. Soc. Am. B,1996,13(2):735-741.

    [41] KACZKAN M,FRUKACZ Z,MALINOWSKI M. Infrared to visible wavelength upconversion in Sm3+ activated YAG crystals
    [J]. J. Alloys Compd.,2001,323-324:736-739.

    [42] LAVIN V,LAHOZ F,MARTIN I R,et al.. Infrared-to-visible photon avalanche upconversion dynamics in Ho3+ doped fluorozirconate glasses at room temperature
    [J]. Opt. Mater.,2005,27(12):1754-1761.

    [43] KUMAR G A,MARTINEZ A,MEJIA E. Fluorescence and upconversion spectral studies of Ho3+ in alkali bismuth gallage glasses
    [J]. J. Alloys Compd.,2004,365(1):117-120.

    [44] LAHOZ F,MARTIN I R,BRIONES A. Infrared laser induced photon avalanche upconversion in Ho3+-Yb3+ codoped fluoroindate glasses
    [J]. J. Appl. Phys.,2004,95(6):2957-2962.

    [45] YANG L M,SONG H W,YU L X,et al.. Unusual power-dependent and time-dependent upconversion luminescence in nanocrystals Y2O3∶ Ho3+/Yb3+
    [J]. J. Lumin.,2006,116(1):101-106.

    [46] VALIENTE R,WENGER O S,GUDEL H U. Upconversion luminescence in Yb3+ doped CsMnCl3:Spectroscopy, dynamics, and mechanisms
    [J]. J. Chem. Phys.,2002,116(12):5196-5204.

    [47] QIN G S,QIN W P,HUANG S H. Up-converting Yb3+-Er3+ co-doped amorphous fluoride thin films prepared by pulsed-laser deposition for visible light source
    [J]. Solid State Commun.,2001,120(2):211-214.

    [48] XU S Q,ZHANG J J,DAI S X,et al.. Host dependent frequency upconversion of Er3+ doped oxyfluoride tellurite glasses
    [J]. J. Alloys Compd.,2004,376(11):L1-L4.

    [49] LIU G K,JACQUIER B. Spectroscopic Properties of Rare Earths in Optical Materials
    [M]. Tsinghua University Press,Springer Press,2005:277.

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