Volume 12 Issue 5
Oct.  2019
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Article Contents
LIU Hui-wen, YAO Dong, LIU Yi, ZHANG Hao. Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications[J]. Chinese Optics, 2019, 12(5): 933-951. doi: 10.3788/CO.20191205.0933
Citation: LIU Hui-wen, YAO Dong, LIU Yi, ZHANG Hao. Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications[J]. Chinese Optics, 2019, 12(5): 933-951. doi: 10.3788/CO.20191205.0933

Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications

doi: 10.3788/CO.20191205.0933
Funds:

the National Key Research and Development Program of China 2016YFB0401701

National Natural Science Foundation of China 21773088

National Natural Science Foundation of China 51425303

JLU Science and Technology Innovative Research Team 2017TD-06

the Jilin Province Science and Technology Research 20190103024JH

More Information
  • Author Bio:

    LIU Hui-wen (1993-), Ph.D.candidate, State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun.Her research interests are on the synthesis of perovskite nanocrystals and their applications in LEDs.E-mail:liuhuiwenjlu@163.com

    ZHANG Hao (1976-), Professor, State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun.His research interests are on the synthesis and controllable self-assembly of photoelectric functional nanocrystals and polymer-based nanocomposites.E-mail:hao_zhang@jlu.edu.cn

  • Corresponding author: ZHANG Hao, E-mail:hao_zhang@jlu.edu.cn
  • Received Date: 10 Apr 2019
  • Rev Recd Date: 07 May 2019
  • Publish Date: 01 Oct 2019
  • Colloidal Mn2+ doped CsPbX3(X=Cl, Br, I) nanocrystals(NCs) are being explored extensively as alternative emitting materials, wherein highly efficient optical and optoelectronic processes can be achieved. Mn2+ doping in perovskite NCs also reveals several new fundamental aspects of doping and new dopant-induced optical properties through different methods of synthesis. Mn2+ doping exists in wide-band-gap perovskite hosts where the excitation energy is transferred to an Mn d-state, resulting in short-range tunable yellow-orange d-d emissions. Enormous efforts have been expended on understanding the doping process and designing highly efficient doped NCs. The unique electronic and fluorescent properties endow these Mn2+ doped perovskite NCs with various optoelectronic applications in light-emitting diodes(LEDs) and solar cells. Combining all these facts, this review focuses on the recent progress in synthesis methods, emission mechanism, and potential applications of Mn2+ doped CsPbX3 perovskite NCs and provides an outline for plausible future studies.

     

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      沈阳化工大学材料科学与工程学院 沈阳 110142

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