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Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications

LIU Hui-wen YAO Dong LIU Yi ZHANG Hao

刘慧雯, 姚栋, 刘轶, 张皓. 锰离子掺杂纯无机钙钛矿纳米晶及应用[J]. 中国光学(中英文), 2019, 12(5): 933-951. doi: 10.3788/CO.20191205.0933
引用本文: 刘慧雯, 姚栋, 刘轶, 张皓. 锰离子掺杂纯无机钙钛矿纳米晶及应用[J]. 中国光学(中英文), 2019, 12(5): 933-951. doi: 10.3788/CO.20191205.0933
LIU Hui-wen, YAO Dong, LIU Yi, ZHANG Hao. Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications[J]. Chinese Optics, 2019, 12(5): 933-951. doi: 10.3788/CO.20191205.0933
Citation: LIU Hui-wen, YAO Dong, LIU Yi, ZHANG Hao. Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications[J]. Chinese Optics, 2019, 12(5): 933-951. doi: 10.3788/CO.20191205.0933

锰离子掺杂纯无机钙钛矿纳米晶及应用

基金项目: 

中国国家重点研发计划 2016YFB0401701

国家自然科学基金 21773088

国家自然科学基金 51425303

吉林大学科技创新研究团队 2017TD-06

吉林省科技发展计划 20190103024JH

详细信息
  • 中图分类号: O631

Mn2+-doped CsPbX3 (X=Cl, Br and I) perovskite nanocrystals and their applications

doi: 10.3788/CO.20191205.0933
Funds: 

the National Key Research and Development Program of China 2016YFB0401701

National Natural Science Foundation of China 21773088

National Natural Science Foundation of China 51425303

JLU Science and Technology Innovative Research Team 2017TD-06

the Jilin Province Science and Technology Research 20190103024JH

More Information
    Author Bio:

    LIU Hui-wen (1993-), Ph.D.candidate, State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun.Her research interests are on the synthesis of perovskite nanocrystals and their applications in LEDs.E-mail:liuhuiwenjlu@163.com

    ZHANG Hao (1976-), Professor, State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun.His research interests are on the synthesis and controllable self-assembly of photoelectric functional nanocrystals and polymer-based nanocomposites.E-mail:hao_zhang@jlu.edu.cn

    Corresponding author: ZHANG Hao, E-mail:hao_zhang@jlu.edu.cn
  • 摘要: 胶体锰离子掺杂的纯无机钙钛矿纳米晶由于其优异的光电性质,使其作为一种新兴的荧光发射材料,被研究者们广泛研究。不仅如此,纯无机钙钛矿纳米晶的锰离子掺杂行为也揭示了由于掺杂过程和掺杂剂本身引起的新的光学性质。通过不同的合成方法和选择不同的锰前驱体可以实现不同的掺杂行为,以及由此引发不同的荧光性质。在高带隙钙钛矿主体中进行锰离子掺杂时,其中激发能量由钙钛矿主体转移到掺杂锰离子位点的d态,进而产生橙黄色d-d发射荧光。研究者们一直致力于理解锰离子掺杂过程并由此设计高效掺杂的纳米晶。这些锰离子掺杂的钙钛矿纳米晶由于具有独特的电子和光学特性使其在发光二极管和太阳能电池等应用中发挥了巨大的作用。结合之前的相关工作和进展,本综述重点总结了锰离子掺杂的纯无机钙钛矿纳米晶的合成方法、发光来源、发光机理和潜在应用的最新进展,并提出了未来潜在合理的研究方向。

     

  • Figure 1.  Summary of various synthesis methods for the synthesis of Mn2+-doped CsPbX3 NCs. (a)Sketch of the hot-injection method. (b)Scheme of LARP synthesis approach. (c)Room temperature post-synthesis method. (d)Microwave-assisted synthesis method. (e)Solvothermal synthesis method

    Figure 2.  Summary of the selection of Mn sources for various synthesis methods of the Mn2+-doped CsPbX3 NCs. The most used MnCl2(a) and (b)MnBr2 with the aid of HBr(c) MnAc2 with the aid of HCl(d) Mn-stearate(e) manganese acetate, manganese acetylacetonate, and manganese halides with the aid of benzoyl halide(f) as the Mn sources participated in the reaction

    Figure 3.  (a) Sketch of 0D CsPbX3 QDs, (b) and (c)Mn2+-doped 0D CsPbX3 QDs, (d)sketch of 2D CsPbX3NSs, (e) and (f)Mn2+-doped 2D CsPbX3NSs or NPLs, (g-j) TEM images of NCs with different Mn2+ substitution ratios(color version please see in the journal website)

    Figure 4.  (a) The host CsPbX3 band gap and relative positions of Mn2+4T1 and 6A1 states, (b)PDOS of CsPbCl3, CsPb0.875Mn0.125Cl3 and CsPb0.75Mn0.25Cl3, respectively, (c)the synthesis scheme of CsPbxM1-xBr3 NCs by triggering Cs4PbBr6 NCs transformation with MnBr2 salts, (d-e)overview of enhanced stability in optical and structural properties of CsPbxMn1-xI3 NCs(color version please see in the journal website)

    Figure 5.  (a) and (b) Mn2+-doped CsPbX3 NCs as color-converting materials for LEDs. (c)LEDs with white color emission. (d)Mn2+-doped CsPbBr3 NCs for electroluminescent LED devices. (e) and (f) Mn2+-doped CsPbX3 NCs for solar cells

    Table  1.   Comparison of the performance parameters of PLEDs based on different Mn-substitution ratio

    Von
    (V)
    Max
    EQE(%)
    Max.CE
    (cd·A-1)
    Max.PE
    (lm·W-1)
    Device structure
    PLED-pure 3.6 0.81 3.71 0.70 ITO/poly-TPD orPVK/QDs/TPBI/LiF/Al
    PLED-Mn2.6 3.5 0.95 4.33 0.72 ITO/poly-TPD orPVK/QDs/TPBI/LiF/Al
    PLED-Mn3.8 4.2 1.49 6.41 1.14 ITO/poly-TPD orPVK/QDs/TPBI/LiF/Al
    下载: 导出CSV

    Table  2.   Comparison of the performance parameters of PSCs based on different CsPbBrI2 films

    Jsc(mA/cm2) Voc/V FF/% PCE/% Jsc(EQE)(mA/cm2)
    MnCl2-0.5% 14.21 1.133 76.8 12.36 13.86
    MnCl2-1% 14.29 1.144 79.9 13.07 13.93
    MnCl2-2% 14.37 1.172 80.0 13.47 14.09
    下载: 导出CSV

    Table  3.   Key J-V parameters of PSCs with different coated layer thicknesses of CsPbCl3:0.1Mn QDs

    QDs(mg/mL) Jsc(mA/cm2) Voc/V FF/% PCE/%
    CsPbCl3-xMn 1 21.42 1.105 76.4 18.08
    CsPbCl3-xMn 5 22.03 1.105 76.3 18.57
    CsPbCl3-xMn 20 20.73 1.105 76.6 17.55
    下载: 导出CSV
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  • 收稿日期:  2019-04-10
  • 修回日期:  2019-05-07
  • 刊出日期:  2019-10-01

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