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近红外光谱法检测乙醇柴油主要性能指标

欧阳爱国 唐天义 王海阳 刘燕德

欧阳爱国, 唐天义, 王海阳, 刘燕德. 近红外光谱法检测乙醇柴油主要性能指标[J]. 中国光学(中英文), 2017, 10(3): 363-369. doi: 10.3788/CO.20171003.0363
引用本文: 欧阳爱国, 唐天义, 王海阳, 刘燕德. 近红外光谱法检测乙醇柴油主要性能指标[J]. 中国光学(中英文), 2017, 10(3): 363-369. doi: 10.3788/CO.20171003.0363
OUYANG Ai-guo, TANG Tian-yi, WANG Hai-yang, LIU Yan-de. Detection of key performance indicators of ethanol diesel by the infrared spectroscopy method[J]. Chinese Optics, 2017, 10(3): 363-369. doi: 10.3788/CO.20171003.0363
Citation: OUYANG Ai-guo, TANG Tian-yi, WANG Hai-yang, LIU Yan-de. Detection of key performance indicators of ethanol diesel by the infrared spectroscopy method[J]. Chinese Optics, 2017, 10(3): 363-369. doi: 10.3788/CO.20171003.0363

近红外光谱法检测乙醇柴油主要性能指标

doi: 10.3788/CO.20171003.0363
基金项目: 

南方山地果园智能化管理技术与装备协同创新中心资助项目 Gan Jiao high [2014]60

详细信息
    作者简介:

    欧阳爱国(1968-), 男, 江西常德人, 学士, 教授, 主要从事车辆性能检测方面的研究。E-mail:ouyangaiguo1968711@163.com

    通讯作者:

    欧阳爱国, E-mail:ouyangaiguo1968711@163.com

  • 中图分类号: O657.33;TE626.9

Detection of key performance indicators of ethanol diesel by the infrared spectroscopy method

Funds: 

Foundation Project of Intelligent Management Technology and Equipment Collaborative Innovation Center of the Southern Mountain Orchard Gan Jiao high [2014]60

  • 摘要: 乙醇柴油是柴油替代品的一种,它的使用越来越广泛,乙醇柴油品质由许多指标决定,采用传统方法检测这些指标不仅价格昂贵而且耗时长。近红外光谱技术是一种廉价、快速实时在线检测乙醇柴油品质的有效方法。本文采用近红外光谱技术结合最小二乘支持向量机检测了乙醇柴油的密度、粘度和乙醇含量,比较了线性和非线性校正技术(主成分回归、偏最小二乘回归和最小二乘支持向量机)对乙醇柴油品质的分析效果,同时也比较了不同预处理方法对预测模型能力的影响。实验结果表明,最小二乘支持向量机优于主成分回归和偏最小二乘回归模型,其对乙醇柴油密度、粘度、乙醇含量建模效果最优,相关系数分别是0.995 8、0.995 7和0.995 3;预测均方根误差分别为0.000 68、0.011 3和0.571 4。

     

  • 图 1  乙醇柴油近红外光谱

    Figure 1.  Near infrared spectra of ethanol diesel

    图 2  乙醇柴油密度、粘度和乙醇含量在PCR, PLS, LSSVM建模下的RMSEP

    Figure 2.  RMSEP of ethanol diesel oil density, viscosity and ethanol content under PCR, PLS and LSSVM modeling RMSEP

    图 3  最小二乘支持向量机最佳模型预测结果

    Figure 3.  Predicted results of optimized LSSVM model

    表  1  32种浓度乙醇柴油

    Table  1.   Ethanol diesel with 32 kinds of concentration (%, v/v)

    序号浓度/%序号浓度/%序号浓度/%序号浓度/%
    10.695.61710.62515.6
    21.2106.21811.22616.2
    31.8116.81911.82716.8
    42.4127.42012.42817.4
    53.0138.02113.02918.0
    63.6148.62213.63018.6
    74.2159.22314.23119.2
    85.01610.02415.03220.0
    下载: 导出CSV

    表  2  PCR方法对乙醇柴油密度、粘度、乙醇含量的性能预测

    Table  2.   Prediction results of principal component regression(PCR) approach for ethanol diesel properties including:density, viscosity, ethanol content

    乙醇柴油性质最优预处理方法主成分PCR2RMSEP
    密度/(g·cm-3)MSC-SG160.909 40.001 7
    粘度/(mPa·s)MSC-SG160.902 40.038 6
    乙醇含量(体积比)(%)MSC-SG140.883 01.968 7
    下载: 导出CSV

    表  3  PLS方法对乙醇柴油密度、粘度、乙醇含量的性能预测

    Table  3.   Prediction results of partial least squares (PLS) regression approach for ethanol diesel properties including:density, viscosity, ethanol content

    乙醇柴油性质最优预处理方法主因子数R2RMSEP
    密度/(g·cm-3)SG80.955 30.001 5
    粘度/(mPa·s)SG80.951 50.027 2
    乙醇含量(体积比)(%)SG80.951 01.273 7
    下载: 导出CSV

    表  4  LSSVM对乙醇柴油密度、粘度、乙醇含量的性能预测

    Table  4.   Prediction results of least squares support vector machine (LSSVM) regression approach for ethanol diesel properties including:density, viscosity, ethanol content

    乙醇柴油性质最优预处理方法[gamma, sig2]R2RMSEP
    密度/(g·cm-3)SGD1-SG131 969, 2 0470.995 80.000 68
    粘度/(mPa·s)SNV-SG111 607, 5 6900.995 70.011 3
    乙醇含量(体积比)(%)SG28 707, 5 9630.995 30.571 4
    下载: 导出CSV
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  • 收稿日期:  2017-01-25
  • 修回日期:  2017-03-22
  • 刊出日期:  2017-06-01

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