Volume 12 Issue 6
Dec.  2019
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Article Contents
HU Yi, HU Geng-xin, ZHANG Jie-jing, SANG Dan-dan, LI Yi-kun, GAO Shi-yong. Fabrication of ZnO nanorods/CdS quantum dots and its detection performance in UV-Visible waveband[J]. Chinese Optics, 2019, 12(6): 1271-1278. doi: 10.3788/CO.20191206.1271
Citation: HU Yi, HU Geng-xin, ZHANG Jie-jing, SANG Dan-dan, LI Yi-kun, GAO Shi-yong. Fabrication of ZnO nanorods/CdS quantum dots and its detection performance in UV-Visible waveband[J]. Chinese Optics, 2019, 12(6): 1271-1278. doi: 10.3788/CO.20191206.1271

Fabrication of ZnO nanorods/CdS quantum dots and its detection performance in UV-Visible waveband

doi: 10.3788/CO.20191206.1271

Postdoctoral Science Foundation of Heilongjiang Province LBH-Q16104

Natural Science Foundation of Shandong Province ZR2017QA013

More Information
  • Corresponding author: GAO Shi-yong, E-mail:gaoshiyong@hit.edu.cn
  • Received Date: 29 Jan 2019
  • Rev Recd Date: 03 Mar 2019
  • Publish Date: 01 Dec 2019
  • ZnO nanorods were prepared on ITO substrate using the hydrothermal method and then CdS quantum dots were synthesized on the ZnO nanorods with the chemical bath deposition method. The morphologies and crystalline structure of the as-prepared samples were characterized by SEM and XRD, respectively. The results indicated that after the chemical bath deposition, spherical CdS quantum dots were evenly coated on the surface of ZnO nanorods with good crystalline quality. The photodetectors made up of ZnO nanorods and ZnO nanorods/CdS quantum dots showed good response under ultraviolet(UV) irradiation. The photocurrent of ZnO nanorods/CdS quantum dots detector(0.52 mA) was 7 times higher than that of ZnO nanorods. In addition, the photodetector based on ZnO nanorods/CdS quantum dots exhibited good response to green and blue light.


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  • [1]
    张吉英, 蒋大勇, 鞠振刚, 等.用于日盲波段的MgZnO薄膜材料和紫外探测器[J].中国光学与应用光学, 2008, 1(1):80-84. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK200802700006

    ZHANG J Y, JIANG D Y, JU ZH G, et al.. MgxZn1-xO thin film and UV detector for solar-blind wavelength[J]. Chinese Journal of Optics and Applied Optics, 2008, 1(1):80-84.(in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK200802700006
    FANG Y J, DONG Q F, SHAO Y CH, et al.. Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination[J]. Nature Photonics, 2015, 9(10):679-686. doi: 10.1038/nphoton.2015.156
    王世涛, 张伟, 王强.红外探测器件在低温背景下的探测率测试[J].光学 精密工程, 2012, 20(3):484-491. http://d.old.wanfangdata.com.cn/Periodical/gxjmgc201203005

    WANG SH T, ZHANG W, WANG Q. Measurement for detectivity of infrared detectors in low temperature background[J]. Opt. Precision Eng., 2012, 20(3):484-491.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/gxjmgc201203005
    HU L, ZHU L P, HE H P, et al.. Colloidal chemically fabricated ZnO:Cu-based photodetector with extended UV-visible detection waveband[J]. Nanoscale, 2013, 5(20):9577-9581. doi: 10.1039/c3nr01979a
    唐小强, 陈裕雲, 罗燕妮, 等.基于TiO2 NRs@ZnIn2S4 NSs复合材料的谷胱甘肽光电化学传感器的构建与应用[J].分析化学, 2019, 47(8):1188-1194. http://d.old.wanfangdata.com.cn/Periodical/fxhx201908009

    TANG X Q, CHEN Y Y, LUO Y N, et al.. A novel glutathione photoelectrochemical sensor based on titanium dioxide nanorods@ZnIn2S4 nansheets nanocomposites[J]. Chinese J. Anal. Chem., 2019, 47(8):1188-1194.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/fxhx201908009
    LI X D, GAO C T, DUAN H G, et al.. High-performance photoelectrochemical-type self-powered UV photodetector using epitaxial TiO2/SnO2 branched heterojunction nanostructure[J]. Small, 2013, 9(11):2005-2011. doi: 10.1002/smll.201202408
    胡轶, 徐思伟, 李想, 等.自供能ZnO/ZnS异质结紫外探测器的性能研究[J].材料研究学报, 2019, 33(7):523-529. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=clyjxb201907006

    HU Y, XU S W, LI X, et al.. Performance of self-powered UV photodetector based on ZnO/ZnS heterojunction[J]. Chin. J. Mater. Res., 2019, 33(7):523-529.(in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=clyjxb201907006
    胡明江, 晋兵营.基于CuO/ZnO异质结纳米花的薄膜型丙酮传感器研究[J].分析化学, 2019, 47(3):363-370. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fxhx201903005

    HU M J, JIN B Y. Research on film type acetone sensor based on copper oxide/zinc oxide heterostructure nanoflower[J]. Chinese J. Anal. Chem., 2019, 47(3):363-370.(in Chinese) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fxhx201903005
    翟英娇, 李金华, 陈新影, 等.镉掺杂氧化锌纳米花的制备及其光催化活性[J].中国光学, 2014, 7(1):124-130. http://www.chineseoptics.net.cn/CN/abstract/abstract9105.shtml

    ZHAI Y J, LI J H, CHEN X Y, et al.. Synthesis and characterization of Cd-doped ZnO nanoflowers and its photocatalytic activity[J]. Chinese Optics, 2014, 7(1):124-130.(in Chinese) http://www.chineseoptics.net.cn/CN/abstract/abstract9105.shtml
    宋志明, 赵东旭, 郭振, 等.ZnO纳米线紫外探测器的制备和快速响应性能的研究[J].物理学报, 2012, 61(5):052901. http://d.old.wanfangdata.com.cn/Periodical/wlxb201205016

    SONG ZH M, ZHAO D X, GUO ZH, et al.. Fabrication and fast photoresponse properties of ZnO nanowires photodetectors[J]. Acta Physica Sinica, 2012, 61(5):052901.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/wlxb201205016
    KHAYATIAN A, ASGAR V, RAMAZANI A, et al.. Diameter-controlled synthesis of ZnO nanorods on Fe-doped ZnO seed layer and enhanced photodetection performance[J]. Materials Research Bulletin, 2017, 94:77-84. doi: 10.1016/j.materresbull.2017.05.023
    YAN SH K, RAI S C, ZHENG ZH, et al.. Piezophototronic effect enhanced UV/Visible photodetector based on ZnO/ZnSe heterostructure core/shell nanowire array and its self-powered performance[J]. Advanced Electronic Materials, 2016, 2(12):1600242. doi: 10.1002/aelm.201600242
    陈全友, 谭学才, 杜方凯, 等.基于CdS敏化Fe:TiO2纳米片的光电传感器对Cu2+的检测[J].分析化学, 2018, 46(2):232-238. http://d.old.wanfangdata.com.cn/Periodical/fxhx201802012

    CHEN Q Y, TAN X C, DU F K, et al.. A photoelectrochemical sensor based on CdS sensitized Fe:TiO2 nanosheets for determination of Cu2+[J]. Chinese J. Anal. Chem., 2018, 46(2):232-238.(in Chinese) http://d.old.wanfangdata.com.cn/Periodical/fxhx201802012
    WEI R B, KUANG P Y, CHENG H, et al.. Plasmon-enhanced photoelectrochemical water splitting on gold NPs decorated ZnO/CdS nanotube arrays[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(5):4249-4257. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=857fa097309c5a3892f99a419177e3d7
    DING M, YAO N N, WANG CH G, et al.. ZnO@CdS core-shell heterostructures:fabrication, enhanced photocatalytic, and photoelectrochemical performance[J]. Nanoscale Research Letters, 2016, 11(1):205. doi: 10.1186/s11671-016-1432-7
    ZHAO H, DONG Y M, JIANG P P, et al.. Light-assisted preparation of a ZnO/CdS nanocomposite for enhanced photocatalytic H2 evolution:an insight into importance of in situ generated ZnS[J]. ACS Sustainable Chemistry & Engineering, 2015, 3(5):969-977. doi: 10.1021/acssuschemeng.5b00102
    TAK Y, HONG S J, LEE J S, et al.. Fabrication of ZnO/CdS core/shell nanowire arrays for efficient solar energy conversion[J]. Journal of Materials Chemistry, 2009, 19(33):5945-5951. doi: 10.1039/b904993b
    SALEM M, AKIR S, MASSOUDI I, et al.. Photoelectrochemical and optical properties tuning of graphene-ZnO nanocomposites[J]. Journal of Alloys and Compounds, 2018, 767:982-987. doi: 10.1016/j.jallcom.2018.07.202
    LI P, HOU CH CH, ZHANG X H, et al.. Ethylenediamine-functionalized CdS/tetra(4-carboxyphenyl)porphyrin iron(Ⅲ) chloride hybrid system for enhanced CO2 photoreduction[J]. Applied Surface Science, 2018, 459:292-299. doi: 10.1016/j.apsusc.2018.08.002
    SELMAN A M, HASSAN Z. Highly sensitive fast-response UV photodiode fabricated from rutile TiO2 nanorod array on silicon substrate[J]. Sensors and Actuators A:Physical, 2015, 221:15-21. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=8e5be87afe053f7a1f60c348a1a4ef5d
    KUMAR P S, RAJ A D, MANGALARAJ D, et al.. Hydrophobic ZnO nanostructured thin films on glass substrate by simple successive ionic layer absorption and reaction(SILAR) method[J]. Thin Solid Films, 2010, 518(24):e183-e186. doi: 10.1016/j.tsf.2010.03.094
    LV J P, FANG M H. Photoluminescence study of interstitial oxygen defects in ZnO nanostructures[J]. Materials Letters, 2018, 218:18-21. doi: 10.1016/j.matlet.2018.01.137
    VANALAKAR S A, MALI S S, SURYAWANSHI M P, et al.. Photoluminescence quenching of a CdS nanoparticles/ZnO nanorods core-shell heterogeneous film and its improved photovoltaic performance[J]. Optical Materials, 2014, 37:766-772. doi: 10.1016/j.optmat.2014.09.005
    LAVAND A B, MALGHE Y S. Visible light photocatalytic degradation of 4-chlorophenol using C/ZnO/CdS nanocomposite[J]. Journal of Saudi Chemical Society, 2015, 19(5):471-478. doi: 10.1016/j.jscs.2015.07.001
    KAMBLE A, SINHA B, CHUNG K, et al.. Facile linker free growth of CdS nanoshell on 1-D ZnO:solar cell application[J]. Electronic Materials Letters, 2015, 11(2):171-179. doi: 10.1007/s13391-014-4236-x
    LI B X, WANG Y F. Synthesis, microstructure, and photocatalysis of ZnO/CdS nano-heterostructure[J]. Journal of Physics and Chemistry of Solids, 2011, 72(10):1165-1169. doi: 10.1016/j.jpcs.2011.07.010
    JUN H K, CAREEM M A, AROF A K. A suitable polysulfide electrolyte for CdSe quantum dot-sensitized solar cells[J]. International Journal of Photoenergy, 2013, 2013:942139. http://d.old.wanfangdata.com.cn/OAPaper/oai_doaj-articles_bb2b1d57122900a9cd5a4c0aa43d8912
    李陈欢, 肖丹.多硫电解质对CdS薄膜电池光电性能影响研究[J].化学研究与应用, 2010, 22(8):1042-1045. doi: 10.3969/j.issn.1004-1656.2010.08.015

    LI CH H, XIAO D. Researches on the polysulfide electrolyte effect for CdS thin film photoelectrochemical cells[J]. Chemical Research and Application, 2010, 22(8):1042-1045.(in Chinese) doi: 10.3969/j.issn.1004-1656.2010.08.015
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