基于电荷转移的钙钛矿单晶和多晶材料表面增强拉曼散射研究

于治; 于伟利; 郭春雷

doi:10.3788/CO.20191205.0952

Volume 12 Issue 5

Oct. 2019

Turn off MathJax

Article Contents

Chinese Optics > 2019 > 12(5): 952-963.

YU Zhi, YU Wei-li, GUO Chun-lei. Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites[J]. Chinese Optics, 2019, 12(5): 952-963. doi: 10.3788/CO.20191205.0952

Citation:

YU Zhi, YU Wei-li, GUO Chun-lei. Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites[J]. Chinese Optics, 2019, 12(5): 952-963. doi: 10.3788/CO.20191205.0952

Citation:

PDF( 3500 KB)

Charge transfer induced surface enhanced Raman scattering of single crystal and polycrystal perovskites

doi: 10.3788/CO.20191205.0952

YU Zhi^1
,,
YU Wei-li^{1
,
,},
GUO Chun-lei^{1, 2
,
,}

1.
The Guo China-US Photonics Laboratory, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China
2.
The Institute of Optics, University of Rochester, Rochester, NY 14627, USA

Funds: Supported by National Key R&D Program of China(No.2017YFB1104700); National Natural Science Foundation(No.61705227, No.61774155, No.11774340); Jilin Provincial Science & Technology Development Project (No.20180414019GH); Scientific Research Project of the Chinese Academy of Sciences(No.QYZDB-SSW-SYS038); The Key Program of the International Partnership Program of CAS(No.181722KYSB20160015)

More Information

Author Bio:
YU Zhi (1988-), Ph.D, Assistant Professor, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.His research interests are on interfacial charge transfer based Surface enhanced Raman scattering.E-mail:zhiyu@ciomp.ac.cn

YU Wei-li (1979-), Ph.D, Associate Professor, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.His research interests are on functional nanomaterials researches and its light energy related applications.E-mial:weili.yu@ciomp.ac.cn

GUO Chun-lei (1971-), Ph.D, Professor, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.His research interests are on laser-matter interactions at high intensities, nano-photonics, femtosecond laser surface nano and microstructuring, and surface plasmonics.E-mail:guo@optics.rochester.edu
Corresponding author: YU Wei-li, E-mial:weili.yu@ciomp.ac.cn; GUO Chun-lei, E-mail:guo@optics.rochester.edu
Received Date: 07 Jan 2019
Rev Recd Date: 28 Feb 2019
Publish Date: 01 Oct 2019

Abstract

Abstract

The charge transfer(CT) process plays a key role in the operation of the optoelectronic device system so a better understanding of the interfacial CT property is greatly important. In this paper, Surface Enhanced Raman Scattering(SERS) was utilized to study the interfacial CT property between CuPc and perovskites(single crystal and polycrystalline). The Raman spectra of CuPc adsorbed on the perovskite surface was enhanced. The laser wavelength dependent SERS study indicates that this phenomenon is mainly arising from the CT from the VB band of perovskite to the LUMO band of the CuPc molecules. In comparison, the SERS signal of CuPc molecules adsorbed on a single crystal is much stronger than that on the polycrystalline perovskite. This result indicates that the defect status affects the enhancement ability of the materials. Further study shows that, after the decoration of a thin silver film, the SERS spectra of CuPc on both single crystal and polycrystalline perovskites are further enhanced. The extreme enhancement is not only due to the electromagnetic property of the silver film but also the fact that the SPR of the silver enhances the charge separation of the perovskite, which further promotes the CT process between the substrate and adsorbed molecules. The CT based SERS study shows great potential application value in the field of optoelectronic research.
- SERS,
- perovskite,
- charge transfer,
- CuPc

FullText(HTML)

References(45)

References

[1]	BURSCHKA J, PELLET N, MOON S J, et al.. Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J]. Nature, 2013, 499(7458):316-319. doi: 10.1038/nature12340
[2]	ZHAO Y X, ZHU K.Organic-inorganic hybrid lead halide perovskites for optoelectronic and electronic applications[J]. Chemical Society Reviews, 2016, 45(3):655-689. doi: 10.1039/C4CS00458B
[3]	TAN ZH K, MOGHADDAM R S, LAI M L, et al.. Bright light-emitting diodes based on organometal halide perovskite[J]. Nature Nanotechnology, 2014, 9(9):687-692. doi: 10.1038/nnano.2014.149
[4]	YU W L, LI F, WANG H, et al.. Ultrathin Cu₂O as an efficient inorganic hole transporting material for perovskite solar cells[J]. Nanoscale, 2016, 8(11):6173-6179. doi: 10.1039/C5NR07758C
[5]	SHI D, ADINOLFI V, COMIN R, et al.. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals[J]. Science, 2015, 347(6221):519-522. doi: 10.1126/science.aaa2725
[6]	DONG Q F, FANG Y J, SHAO Y CH, et al.. Electron-hole diffusion lengths>175μm in solution-grown CH₃NH₃PbI₃ single crystals[J]. Science, 2015, 347(6225):967-970. doi: 10.1126/science.aaa5760
[7]	ZHOU H P, CHEN Q, LI G, et al.. Interface engineering of highly efficient perovskite solar cells[J]. Science, 2014, 345(6196):542-546. doi: 10.1126/science.1254050
[8]	HAO F, STOUMPOS C C, CAO D H, et al.. Lead-free solid-state organic-inorganic halide perovskite solar cells[J]. Nature Photonics, 2014, 8(6):489-494. doi: 10.1038/nphoton.2014.82
[9]	MA CH, SHI Y M, HU W J, et al.. Heterostructured WS₂/CH₃NH₃PbI₃photoconductors with suppressed dark current and enhanced photodetectivity[J]. Advanced Materials, 2016, 28(19):3683-3689. doi: 10.1002/adma.201600069
[10]	LIU M ZH, JOHNSTON M B, SNAITH H J.Efficient planar heterojunction perovskite solar cells by vapour deposition[J]. Nature, 2013, 501(7467):395-398. doi: 10.1038/nature12509
[11]	JEON N J, NOH J H, KIM Y C, et al.. Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells[J]. Nature Materials, 2014, 13(9):897-903. doi: 10.1038/nmat4014
[12]	XING G CH, MATHEWS N, SUN SH Y, et al.. Long-range balanced electron-and hole-transport lengths in organic-inorganic CH₃NH₃PbI₃[J]. Science, 2013, 42(6156):344-347.
[13]	STRANKS S D, EPERON G E, GRANCINI G, et al.. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J]. Science, 2013, 342(6156):341-344. doi: 10.1126/science.1243982
[14]	MARCHIORO A, TEUSCHER J, FRIEDRICH D, et al.. Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells[J]. Nature Photonics, 2014, 8(3):250-255. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d63ca0b74c4db18927acc652d2f40017
[15]	EDRI E, KIRMAYER S, MUKHOPADHYAY S, et al.. Elucidating the charge carrier separation and working mechanism of CH₃NH₃PbI_3-xCl_x perovskite solar cells[J]. Nature Communications, 2014, 5:3461. doi: 10.1038/ncomms4461
[16]	BEGUM R, PARIDA M R, ABDELHADY A L, et al.. Engineering interfacial charge transfer in CsPbBr₃ perovskite nanocrystals by heterovalent doping[J]. Journal of the American Chemical Society, 2017, 139(2):731-737. doi: 10.1021/jacs.6b09575
[17]	LIU J X, LENG J, WU K F, et al.. Observation of internal photoinduced electron and hole separation in hybrid two-dimentional perovskite films[J]. Journal of the American Chemical Society, 2017, 139(4):1432-1435. doi: 10.1021/jacs.6b12581
[18]	FLEISCHMANN M, HENDRA P J, MCQUILLAN A J. Ramanspectra of pyridine adsorbed at a silver electrode[J]. Chemical Physics Letters, 1974, 26(2):163-166. doi: 10.1016/0009-2614(74)85388-1
[19]	LOMBARDI J R, BIRKE R L. A unified approach to surface-enhanced Raman spectroscopy[J]. The Journal of Physical Chemistry C, 2008, 112(14):5605-5617. doi: 10.1021/jp800167v
[20]	BELL S E J, SIRIMUTHU N M S. Quantitative surface-enhanced Raman spectroscopy[J]. Chemical Society Reviews, 2008, 37(5):1012-1024. doi: 10.1039/b705965p
[21]	PARK S, YANG P X, CORREDOR P, et al.. Transition metal-coated nanoparticle films:vibrational characterization with surface-enhanced Raman scattering[J]. Journal of the American Chemical Society, 2002, 124(11):2428-2429. doi: 10.1021/ja017406b
[22]	KNEIPP K, MOSKOVITS M, KNEIPP H. Surface-Enhanced Raman Scattering: Physics and Applications[M]. Berlin, Germany: Springer, 2006.
[23]	LOMBARDI J R, BIRKE R L. A unified view of surface-enhanced raman scattering[J]. Accounts of Chemical Research, 2009, 42(6):734-742. doi: 10.1021/ar800249y
[24]	YAMADA H, YAMAMOTO Y, TANI N. Surface-enhanced raman scattering(SERS) of adsorbed molecules on smooth surfaces of metals and a metal-oxide[J]. Chemical Physics Letters, 1982, 86(4):397-400. doi: 10.1016/0009-2614(82)83531-8
[25]	YAMADA H, YAMAMOTO Y. Surface enhanced raman scattering(SERS) of chemisorbed species on various kinds of metals and semiconductors[J]. Surface Science, 1983, 134(1):71-90. doi: 10.1016/0039-6028(83)90312-6
[26]	LING X, XIE L M, FANG Y, et al.. Can graphene be used as a substrate for raman enhancement?[J]. Nano Letters, 2010, 10(2):553-561. doi: 10.1021/nl903414x
[27]	LIVINGSTONE R, ZHOU X C, TAMARGO M C, et al.. Surface enhanced raman spectroscopy of pyridine on CdSe/ZnBeSe quantum dots grown by molecular beam epitaxy[J]. The Journal of Physical Chemistry C, 2010, 114(41):17460-17464. doi: 10.1021/jp105619m
[28]	JI W, KITAHAMA Y, XUE X X, et al.. Generation of pronounced resonance profile of charge-transfer contributions to surface-enhanced raman scattering[J]. The Journal of Physical Chemistry C, 2012, 116(3):2515-2520. doi: 10.1021/jp209947p
[29]	SUN ZH H, WANG CH X, YANG J X, et al.. Nanoparticle metal-semiconductor charge transfer in ZnO/PATP/Ag assemblies by surface-enhanced Raman spectroscopy[J]. The Journal of Physical Chemistry C, 2008, 112(15):6093-6098. doi: 10.1021/jp711240a
[30]	MAO ZH, SONG W, XUE X X, et al.. Multiphonon resonant raman scattering and photoinduced charge-transfer effects at ZnO-molecule interfaces[J]. The Journal of Physical Chemistry C, 2012, 116(51):26908-26918. doi: 10.1021/jp3092573
[31]	WANG X L, WANG Y, SUI H M, et al.. Investigation of charge transfer in Ag/N719/TiO₂ interface by surface-enhanced raman spectroscopy[J]. The Journal of Physical Chemistry C, 2016, 120(24):13078-13086. doi: 10.1021/acs.jpcc.6b03228
[32]	TARAKESHWAR P, PALMA J L, FINKELSTEIN-SHAPIRO D, et al.. SERS as a probe of charge-transfer pathways in hybrid dye/molecule-metal oxide complexes[J]. The Journal of Physical Chemistry C, 2014, 118(7):3774-3782. doi: 10.1021/jp410725w
[33]	YU ZH, YU W L, XING J, et al.. Charge transfer effects on resonance-enhanced raman scattering for molecules adsorbed on single-crystalline perovskite[J]. ACS Photonics, 2018, 5(4):1619-1627. doi: 10.1021/acsphotonics.8b00152
[34]	MACULAN G, SHEIKH A D, ABDELHADY A L, et al.. CH₃NH₃PbCl₃ single crystals:inverse temperature crystallization and visible-blind UV-photodetector[J]. The Journal of Physical Chemistry Letters, 2015, 6(19):3781-3786. doi: 10.1021/acs.jpclett.5b01666
[35]	BAIKIE T, BARROW N S, FANG Y A, et al.. A combined single crystal neutron/X-ray diffraction and solid-state nuclear magnetic resonance study of the hybrid perovskites CH₃NH₃PbX₃(X=I, Br and Cl)[J].Journal of Materials Chemistry A, 2015, 3(17):9298-9307. doi: 10.1039/C5TA01125F
[36]	LING X, FANG W J, LEE Y H, et al.. Raman enhancement effect on two-dimensional layered materials:graphene, h-BN and MoS₂[J]. Nano Letters, 2014, 14(6):3033-3040. doi: 10.1021/nl404610c
[37]	TAN Y, MA L N, GAO ZH B, et al.. Two-dimensional heterostructure as a platform for surface-enhanced raman scattering[J]. Nano Letters, 2017, 17(4):2621-2626. doi: 10.1021/acs.nanolett.7b00412
[38]	BASOVA T V, KOLESOV B A. Raman spectra of copper phthalocyanin:experiment and calculation[J]. Journal of Structural Chemistry, 2000, 41(5):770-777. doi: 10.1023/A:1004802000669
[39]	WANG M F, SPATARU T, LOMBARDI J R, et al.. Time resolved surface enhanced Raman scattering studies of 3-hydroxyflavone on a Ag electrode[J]. The Journal of Physical Chemistry C, 2007, 111(7):3044-3052. doi: 10.1021/jp0650937
[40]	WANG M F, TESLOVA T, XU F, et al.. Raman and surface enhanced Raman scattering of 3-hydroxyflavone[J]. The Journal of Physical Chemistry C, 2007, 111(7):3038-3043. doi: 10.1021/jp062100i
[41]	KIM Y C, YANG T Y, JEON N J, et al.. Engineering interface structures between lead halide perovskite and copper phthalocyanine for efficient and stable perovskite solar cells[J]. Energy & Environmental Science, 2017, 10(10):2109-2116. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=f2ae225853e3af2cc653c9b936edfb7a
[42]	NIU B J, WU L L, TANG W, et al.. Enhancement of near-band edge emission of Au/ZnO composite nanobelts by surface plasmon resonance[J]. CrystEngComm, 2011, 13(11):3678-3681. doi: 10.1039/c1ce05175j
[43]	SU Y H, TU S L, TSENG S W, et al.. Influence of surface plasmon resonance on the emission intermittency of photoluminescence from gold nano-sea-urchins[J]. Nanoscale, 2010, 2(12):2639-2646. doi: 10.1039/c0nr00330a
[44]	BABA A, AOKI N, SHINBO K, et al.. Grating-coupled surface plasmon enhanced short-circuit current in organic thin-film photovoltaic cells[J]. ACS Applied Materials & Interfaces, 2011, 3(6):2080-2084. doi: 10.1021/am200304x
[45]	SU Y H, KE Y F, CAI SH L, et al.. Surface plasmon resonance of layer-by-layer gold nanoparticles induced photoelectric current in environmentally-friendly plasmon-sensitized solar cell[J]. Light:Science & Applications, 2012, 1(6):e14. doi: 10.1038/lsa.2012.14