Ag@SiO<sub>2</sub>纳米核壳结构对铒碲发光玻璃的发光增强机制

陈晓波; 李崧; 赵国营; 刘洪珍; 郭敬华; 马瑜; 王克志; 耿珠峰

doi:10.37188/CO.2021-0142

Volume 15 Issue 2

Mar. 2022

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Article Contents

Chinese Optics > 2022 > 15(2): 224-232.

CHEN Xiao-bo, LI Song, ZHAO Guo-ying, LIU Hong-Zhen, GUO Jing-hua, MA Yu, WANG Ke-zhi, GENG Zhu-feng. Luminescence enhancement mechanism of Er3+ ions by Ag@SiO2 core-shell nanostructure in tellurite glass[J]. Chinese Optics, 2022, 15(2): 224-232. doi: 10.37188/CO.2021-0142

Citation:

CHEN Xiao-bo, LI Song, ZHAO Guo-ying, LIU Hong-Zhen, GUO Jing-hua, MA Yu, WANG Ke-zhi, GENG Zhu-feng. Luminescence enhancement mechanism of Er³⁺ ions by Ag@SiO₂ core-shell nanostructure in tellurite glass[J]. Chinese Optics, 2022, 15(2): 224-232. doi: 10.37188/CO.2021-0142

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Luminescence enhancement mechanism of Er³⁺ ions by Ag@SiO₂ core-shell nanostructure in tellurite glass

doi: 10.37188/CO.2021-0142

CHEN Xiao-bo^{1
,
,},
LI Song^1
,,
ZHAO Guo-ying^2
,,
LIU Hong-Zhen^{3, 4
,},
GUO Jing-hua^1
,,
MA Yu^2
,,
WANG Ke-zhi^5
,,
GENG Zhu-feng^1
,

1.
Applied Optics Beijing Area Major Laboratory, Beijing Normal University, Beijing 100875, China
2.
School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 200235, China
3.
State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
4.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 China
5.
Chemistry College, Beijing Normal University, Beijing 100875, China

Funds: Supported by the National Natural Science Foundation of China (No. 51972020, No. 51472028)；the Fundamental Research Funds of Central Universities of China (No. 2017TZ01)

More Information

Corresponding author: chen78xb@sina.com
Received Date: 17 Jul 2021
Rev Recd Date: 09 Aug 2021
Accepted Date: 18 Nov 2021

Available Online: 18 Nov 2021

Publish Date: 21 Mar 2022

Abstract

Abstract

In this paper, we introduce a prefabricabed Ag@SiO₂ nanostructure directly into tellurite luminescence glass composed of 70TeO₂-25ZnO-5La₂O₃-0.5Er₂O₃. We find that the maximum enhancement of visible and infrared excitation spectra intensity of (A) Ag (1.6×10⁻⁶ mol/L)@SiO₂(40 nm) @Er³⁺ (0.5%): tellurite glass relative to (B) Er³⁺ (0.5%): tellurite glass is about 149.0% and 161.5%, respectively. Their maximum enhancement of visible and infrared luminescence spectra intensity is 155.2% and 151.6%, respectively. We also find that sample (A) has a larger lifespan compared to sample (B). Because the surface plasmon absorption peak of Ag@SiO₂ is located at 546.0 nm, it completely resonates with the luminescence peak of erbium ions which are also at 546.0 nm. Therefore, the resonance enhancement action of Ag@SiO₂ on the luminescence of erbium-doped tellurite luminescence glass is significant. Thanks to the advantages of the step-by-step realization of the silver nano core-shell structure and the production of glass, it can successfully and smoothly control the size of Ag@SiO₂. It also has the advantage of strong operability in the manufacturing process of Ag@SiO₂@Er: telluride luminescence glass. Its costs are also minor. Moreover, it can not only ensure that the silver is not oxidized, but it can also successfully control the distance between the rare earth ion luminescence center and the silver surface plasma. It can also successfully reduce the back energy transfer, which allows the silver surface plasma to more effectively enhance the intensity of photo-luminescence.
- Ag@SiO₂ core-shell nanostructure,
- luminescence enhancement,
- surface plasmon

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References(23)

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