激光诱导击穿光谱对金属、陶瓷文物成分的表面及深度分布分析

李晨毓; 曲亮; 高飞; 段鸿莺; 关明; 刘瀚文; 邹非池

doi:10.37188/CO.2020-0112

Volume 13 Issue 6

Dec. 2020

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Chinese Optics > 2020 > 13(6): 1239-1248.

LI Chen-yu, QU Liang, GAO Fei, DUAN Hong-ying, GUAN Ming, LIU Han-wen, ZOU Fei-chi. Composition analysis of the surface and depth distribution of metal and ceramic cultural relics by laser-induced breakdown spectroscopy[J]. Chinese Optics, 2020, 13(6): 1239-1248. doi: 10.37188/CO.2020-0112

Citation:

LI Chen-yu, QU Liang, GAO Fei, DUAN Hong-ying, GUAN Ming, LIU Han-wen, ZOU Fei-chi. Composition analysis of the surface and depth distribution of metal and ceramic cultural relics by laser-induced breakdown spectroscopy[J]. Chinese Optics, 2020, 13(6): 1239-1248. doi: 10.37188/CO.2020-0112

Citation:

LI Chen-yu, QU Liang, GAO Fei, DUAN Hong-ying, GUAN Ming, LIU Han-wen, ZOU Fei-chi. Composition analysis of the surface and depth distribution of metal and ceramic cultural relics by laser-induced breakdown spectroscopy[J]. Chinese Optics, 2020, 13(6): 1239-1248. doi: 10.37188/CO.2020-0112

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Composition analysis of the surface and depth distribution of metal and ceramic cultural relics by laser-induced breakdown spectroscopy

doi: 10.37188/CO.2020-0112

Conservation Department, the Palace Museum, Beijing 100009, China

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Corresponding author: lionat528@hotmail.com
Received Date: 30 Jun 2020
Rev Recd Date: 27 Jul 2020

Available Online: 18 Mar 2021

Publish Date: 01 Dec 2020

Abstract

Abstract

Composition analysis of the surface and depth distribution of bronze artifacts excavated from the Chu Tomb in Guozhuang Shangcai, Henan Province and ceramic tiles of Lingzhaoxuan from the Palace Museum are carried out by laser-induced breakdown spectroscopy and laser scanning confocal microscopy. Studies have shown that the elemental distribution of the corroded layer on the surface of bronze is uneven. This corrosion might originate from the surrounding soil environment and surrounding artifacts or ion migration from the artifacts’ insides to their outsides. Luckily, the composition of bronze is relatively simple. The corrosion mechanism of the corroded layer can be understood by analyzing the depth distribution of the composition in bronze, thereby providing a scientific method for its protection. The elemental distribution of ceramic is homogeneous in transparent and colored glaze. Colored glaze includes Boron (B), which could effectively reduce its melting temperature range and surface tension, but there is no boron (B) in transparent glaze. Furthermore, confocal microscope tests of the depth of erosion combined with its spectra can be used to estimate the approximate thickness of different glaze layers.
- laser-induced breakdown spectroscopy,
- surface and depth distribution,
- bronze,
- ceramic

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References(25)

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