Volume 13 Issue 5
Sep.  2020
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LING Xiao, MEI Qing-song. Orthogonal luminescence properties of a single rare-earth activator ion doped upconversion nanoparticles[J]. Chinese Optics, 2020, 13(5): 1158-1170. doi: 10.37188/CO.2020-0020
Citation: LING Xiao, MEI Qing-song. Orthogonal luminescence properties of a single rare-earth activator ion doped upconversion nanoparticles[J]. Chinese Optics, 2020, 13(5): 1158-1170. doi: 10.37188/CO.2020-0020

Orthogonal luminescence properties of a single rare-earth activator ion doped upconversion nanoparticles

Funds:  Supported by National Natural Science Foundation of China (No. 21675038)
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  • Author Bio:

    LING Xiao (1994—), male, born in Wangjiang Country, Anhui Province. In 2013-2017, he studied in the pharmaceutical engineering major, School of Chemistry and Chemical Engineering, Hefei Normal University and obtained the bachelor's degree. Since 2017, he has been studying in the School of Food and Biological Engineering, Hefei University of Technology as a graduate student, while conducting the research on the up-conversion nanoparticles doped with rare earth. E-mail: 18755132335@163.com

    MEI Qing-song (1986—), male, doctor, associate professor and master supervisor. In 2012, he received his doctorate from the University of Science and Technology of China. He is currently engaged in the preparation of up-conversion luminescence nanomaterials and the research of their application in biomedical imaging. E-mail: qsmei@hfut.edu.cn

  • Corresponding author: qsmei@hfut.edu.cn
  • Received Date: 08 Feb 2020
  • Rev Recd Date: 07 Apr 2020
  • Available Online: 16 Sep 2020
  • Publish Date: 01 Oct 2020
  • Upconversion luminescence nanomaterials have attracted widespread attention owing to their special optical properties, while most of them emit single color luminescence. In order to achieve multicolor orthogonal upconversion luminescence and avoid the synthesis complexity and interference between multiple dopant ions, herein, we reported a novel orthogonal emissive upconversion nanoparticle, NaErF4:Yb(19.5%)/Tm(0.5%)@NaYF4:Yb(10%)@NaNdF4:Yb(10%), through thermal decomposition strategy step by step. This novel nanoparticle can give out green luminescence and red luminescence by the energy level transition of Er3+ from 2H11/2,4S3/24I15/2 and 4F9/24I15/2 under the excitation light of 980 nm and 808 nm, respectively. The particles demonstrated uniform size, stable structure and excellent dispersibility. Under the excitation of 980 nm, the emission intensity at 650 nm of red luminescence was approximately 9.46 times more than the emission intensity at 540 nm. Under the excitation of 808 nm, the emission intensity at 540 nm of green luminescence was about 5.39 times more than the emission intensity at 650 nm.

     

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