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连续激光辐照下的TiO2薄膜热传导性质

李代林 杨丹 崔纪琨 王宁 朱化凤

李代林, 杨丹, 崔纪琨, 王宁, 朱化凤. 连续激光辐照下的TiO2薄膜热传导性质[J]. 中国光学(中英文), 2019, 12(3): 628-637. doi: 10.3788/CO.20191203.0628
引用本文: 李代林, 杨丹, 崔纪琨, 王宁, 朱化凤. 连续激光辐照下的TiO2薄膜热传导性质[J]. 中国光学(中英文), 2019, 12(3): 628-637. doi: 10.3788/CO.20191203.0628
LI Dai-lin, YANG Dan, CUI Ji-kun, WANG Ning, ZHU Hua-feng. Heat conduction properties of TiO2 films irradiated by a continuous laser[J]. Chinese Optics, 2019, 12(3): 628-637. doi: 10.3788/CO.20191203.0628
Citation: LI Dai-lin, YANG Dan, CUI Ji-kun, WANG Ning, ZHU Hua-feng. Heat conduction properties of TiO2 films irradiated by a continuous laser[J]. Chinese Optics, 2019, 12(3): 628-637. doi: 10.3788/CO.20191203.0628

连续激光辐照下的TiO2薄膜热传导性质

基金项目: 

国家自然科学基金重大项目 61890964

国家重点研发计划项目 2017YFC1404000

国家科技重大专项 2017ZX05019-006

山东省重点研发计划项目 GG201809250065

中央高校基本科研业务费专项资金 19CX05003A-10

中央高校基本科研业务费专项资金 18CX02046A

详细信息
    作者简介:

    李代林(1973-), 男, 山东青岛人, 副教授, 2004年于上海光学精密机械研究所获得光学工程博士学位, 现为中国石油大学(华东)理学院副教授, 主要从事偏振光相关方面的研究。E-mail:qd_ldl@upc.edu.cn

  • 中图分类号: O436

Heat conduction properties of TiO2 films irradiated by a continuous laser

Funds: 

Major Program of the National Natural Science Foundation of China 61890964

National Key Research and Development Program Project 2017YFC1404000

National Science and Technology Major Project 2017ZX05019-006

Key Research and Development Project of Shandong Province GG201809250065

Fundamental Research Funds for the Central Universities 19CX05003A-10

Fundamental Research Funds for the Central Universities 18CX02046A

More Information
  • 摘要: 热传导规律的研究在激光诱导薄膜材料改性等应用中有着重要的作用,本文针对二氧化碳激光器辐照下的二氧化钛(TiO2)薄膜表面的热效应进行了理论仿真和实验研究。首先,对具有粗糙上表面的TiO2薄膜,利用有限元法构建了连续激光作用下的TiO2薄膜的立体模型并得到了其三维温度场分布。然后使用CO2激光器进行辐照实验,分析了辐照时间和功率等参数对TiO2薄膜形貌、晶相以及颜色的影响。仿真表明,连续激光辐照下TiO2薄膜的瞬态温度场呈高斯分布,且与激光功率、光斑半径、辐照时间等因素有关。当表面温度小于分解温度时,薄膜上表面最大平均温度与激光功率满足线性关系,与光斑半径满足ExpAssoc非线性关系。实验结果表明,激光辐照引起TiO2薄膜材料表面粗糙度降低且颜色变化。激光功率过小或辐照时间过短会导致有效作用面积小且不均匀,反之会产生热形变。结合仿真和实验可知使用功率为6 W,半径为3 mm的连续激光辐照TiO2薄膜10 s时取得的处理效果最优。

     

  • 图 1  MATLAB构建的随机粗糙面型

    Figure 1.  Random rough face constructed by MATLAB

    图 2  几何模型

    Figure 2.  Geometric model

    图 3  0.5、2.5、5、10 s时的上表面等温线及热量传导方向示意图

    Figure 3.  Schematic diagram of isotherm and heat conduction direction on the upper surface at 0.5, 2.5, 5 and 10 s

    图 4  不同激光功率下上表面平均温度-时间曲线

    Figure 4.  Average temperature-time curves of upper surface under different laser powers

    图 5  激光功率与上表面最大平均温度的线性拟合

    Figure 5.  Linear fitting of laser power and maximum mean temperature on the upper surface

    图 6  不同激光功率下上表面中心线上温度分布曲线

    Figure 6.  Temperature distribution curves of upper surface centerline under different laser powers

    图 7  不同激光光斑半径下上表面平均温度-时间曲线

    Figure 7.  Average temperature-time curves of upper surface under different laser radius

    图 8  激光功率与上表面最大平均温度的线性拟合

    Figure 8.  Linear fitting of laser power and maximum mean temperature on the upper surface

    图 9  不同光斑半径下上表面中心线温度分布曲线

    Figure 9.  Temperature distribution curves of upper surface centerline under different laser radius

    图 10  TiO2薄膜显微图

    Figure 10.  Micrograph of TiO2 film

    图 11  TiO2薄膜X射线衍射图谱

    Figure 11.  X-ray diffraction patterns of TiO2 film

    图 12  不同激光功率下的样品表面显微图

    Figure 12.  Micrographs of sample surface under different laser powers

    图 13  不同激光功率下样品的X射线衍射图谱

    Figure 13.  X-ray diffraction spectra of sample with different laser powers

    图 14  不同辐照时间下样品表面显微图

    Figure 14.  Micrographs of sample surface under different irradiation times

    图 15  不同激光辐照时间下样品的X射线衍射图谱

    Figure 15.  X-ray diffraction spectra of sample under different laser irradiation times

    表  1  特性参数

    Table  1.   Characteristic parameters

    Parameters Abbr. Unit Value
    Constant pressure heat capacity C J·Kg-1·K-1 710
    Thickness d mm 0.1
    Length l mm 3.35
    Laser radius a mm 3
    Thermal conductivity k W·m-1· K-1 8.4
    Absorption coefficient α m-1 1 800
    Scattering coefficient σs m-1 2.647
    Density ρ kg·m-3 3 313
    Thermal radiation rate ε 1 0.1
    Surface heat transfer coefficient h W·cm-1· K-1 156
    下载: 导出CSV

    表  2  高斯函数拟合公式及相关系数拟合参数

    Table  2.   Gauss functions and their fitting parameters

    Laser power/W Equation R2
    a 3 y=317.5087+34.03*exp{-2*[(x+1.9595e-4)/5.0947]2} 0.999 1
    b 6 y=341.8283+68.0073*exp{-2*[(x+1.9607e-4)/5.0956]2} 0.999 1
    c 9 y=366.8283+101.9044*exp{-2*[(x+1.9626e-4)/5.0969]2} 0.999 1
    d 12 y=390.3105+135.7004*exp{-2*[(x+1.9633e-4)/5.0986]2} 0.999 1
    e 15 y=414.45+169.3716*exp{-2*[(x+1.9626e-4)/5.1007]2} 0.999 1
    f 18 y=438.5033+202.8924*exp{-2[(x+1.9634e-4)/5.1032]2} 0.999 1
    下载: 导出CSV

    表  3  ExpAssoc函数及Allometricl函数形式及相应拟合参数

    Table  3.   ExpAssoc function, Allometricl function and their fitting parameters

    Function name Equation R2
    ExpAssoc y=188.785 5-1 525.934 4*[1-exp(-x/1.130 9)] 0.999 3
    Allometricl y=983.785 4*x^(-669 9) 0.997 3
    下载: 导出CSV

    表  4  拟合参数

    Table  4.   Fitting parameters

    Laser radius/mm Equation R2
    a 1 y=356.5106+45.9932*exp{-2*[(x-7.6126e-4)/5.5986]2} 0.999 1
    b 2 y=347.7367+630.6741*exp{-2*[(x+5.7232e-5)/2.8963]2} 0.999 2
    c 3 y=356.8013+249.8764*exp{-2*[(x+0.0013)/4.2904]2} 0.999 4
    d 4 y=366.0817+101.9233*exp{-2*[(x+2.1173e-4)/5.0977]2} 0.999 1
    下载: 导出CSV
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出版历程
  • 收稿日期:  2018-08-10
  • 修回日期:  2018-10-12
  • 刊出日期:  2019-06-01

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