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金属离子Bi3+掺杂Lu1-xO3: x%Ho3+荧光粉的发光性能

赵海琴 王林香 庹娟 叶颖

赵海琴, 王林香, 庹娟, 叶颖. 金属离子Bi3+掺杂Lu1-xO3: x%Ho3+荧光粉的发光性能[J]. 中国光学. doi: 10.37188/CO.2019-0222
引用本文: 赵海琴, 王林香, 庹娟, 叶颖. 金属离子Bi3+掺杂Lu1-xO3: x%Ho3+荧光粉的发光性能[J]. 中国光学. doi: 10.37188/CO.2019-0222
ZHAO Hai-qin, WANG Lin-xiang, TUO Juan, YE Ying. Luminescence properties of Bi3+ doped Lu1-xO3: x%Ho3+ metal ion phosphors[J]. Chinese Optics. doi: 10.37188/CO.2019-0222
Citation: ZHAO Hai-qin, WANG Lin-xiang, TUO Juan, YE Ying. Luminescence properties of Bi3+ doped Lu1-xO3: x%Ho3+ metal ion phosphors[J]. Chinese Optics. doi: 10.37188/CO.2019-0222

金属离子Bi3+掺杂Lu1-xO3: x%Ho3+荧光粉的发光性能

doi: 10.37188/CO.2019-0222
基金项目: 新疆维吾尔自治区自然科学基金(2017D01A60);新疆维吾尔自治区2019年研究生教育创新计划项目(XJ2019G229);新疆师范大学新疆矿物发光及其微结构重点实验室招标课题 (KWFG1801)
详细信息
    作者简介:

    赵海琴(1995—),女,甘肃金昌人,硕士,2020 年于新疆师范大学获得硕士学位,主要从事纳米发光材料的制备及其性能研究。E-mail:zhq0928@mail.ustc.edu.cn

    王林香(1979—),女,甘肃秦安人,博士,副教授,2010 年于中国科学技术大学获得博士学位,主要研究纳米发光材料。E-mail:wanglinxiang23@126.com

    通讯作者:

    王林香(1979—),女,甘肃秦安人,博士,副教授,2010 年于中国科学技术大学获得博士学位,主要研究纳米发光材料。E-mail:wanglinxiang23@126.com

  • 中图分类号: O482.31

Luminescence properties of Bi3+ doped Lu1-xO3: x%Ho3+ metal ion phosphors

Funds: Natural Science Foundation of Xinjiang (No. 2017D01A60); 2019 Graduate Education Innovation Program Project of Xinjiang (No. XJ2019G229); Xinjiang Mineral Luminescence and Microstructure Key Laboratory Tender Project of Xinjiang Normal University (No. KWFG1801)
  • 摘要: 采用高温固相法制备了金属离子Bi3+掺杂Lu1-xO3: x%Ho3+系列荧光粉,研究了不同浓度Bi3+掺杂Lu1-xO3: x%Ho3+荧光粉的晶体结构、Lu2O3基质中Bi3+→Ho3+能量传递规律及合成粉体的发光性质。X射线衍射结果表明Bi3+、Ho3+掺杂对Lu2O3的立方相结构没有影响。在322 nm激发波长下发射出位于551 nm处Ho3+5S25I8跃迁;在551 nm监测下,合成的Ho3+,Bi3+共掺杂Lu2O3荧光粉出现Bi3+的322 nm特征激发峰以及Ho3+的448 nm处的5I85F1跃迁。当Bi3+掺杂浓度为1.5%时,Bi3+对Ho3+的能量传递最有效,比单掺Ho3+样品发射强度提高了34.8倍。对于合成1%、1.5%、2%的Bi3+掺杂 Lu98.5%O3: 1.5%Ho3+样品,用980 nm激发比322 nm激发获得在551 nm处光强分别提高 13.3倍、16.8倍、14.2倍。通过计算得到Bi3+和Ho3+之间的能量传递临界距离为2.979 nm,且Bi3+与Ho3+之间的能量传递是通过偶极-四极相互作用来实现的。
  • 图  1  Ho3+、Bi3+掺杂Lu2O3粉末XRD

    Figure  1.  XRD patterns of Ho3+ and Bi3+ doped Lu2O3 powders

    图  2  Lu98.5%O3:1.5%Bi3+和 Lu98.5%O3:1.5%Ho3+样品的激发和发射光谱

    Figure  2.  Excitation and emission spectra of Lu98.5%O3:1.5%Bi3+ and Lu98.5%O3:1.5%Ho3+phosphor samples

    图  3  Lu98.5%-yO3:1.5%Ho3+,y%Bi3+样品的激发光谱(a)和发射光谱(b)

    Figure  3.  Excitation spectra for (a) and emission spectrum for (b) of Lu98.5%O3: 1.5% Ho3+, y%Bi3+ samples

    图  4  Bi3+与Ho3+的能级以及能量传递示意图

    Figure  4.  Schematic diagram of the energy levels and energy transfer of Bi3+ and Ho3+

    图  5  980 nm及322 nm激发下Lu98.5%-yO3:1.5%Ho3+,y%Bi3+样品的发射光谱及强度变化

    Figure  5.  Luminescence spectra and intensity changes of Lu98.5%-yO3: 1.5% Ho3+, y%Bi3+ samples at 980 nm and 322 nm excitation

    图  6  Lu98.5%-yO3:1.5%Ho3+,y%Bi3+荧光粉中Ho3+的荧光衰减曲线

    Figure  6.  Decay curves for the luminescence of Ho3+ in Lu98.5%-yO3:1.5%Ho3+, y%Bi3+phosphors

    图  7  Lu98.5%-yO3:1.5%Ho3+,y%Bi3+荧光粉中Ho3+的Iso/Is与(CBi+CHo)6/3, (CBi+CHo)8/3和(CBi+CHo)10/3关系曲线

    Figure  7.  Dependence Iso/Is of Ho3+ on (CBi+CHo) 6/3, (CBi+CHo) 8/3 and (CBi+CHo) 10/3 in Lu98.5%-yO3:1.5%Ho3+, y%Bi3+ phosphor

    表  1  不同浓度(摩尔分数)Bi3+掺杂Lu2O3:Ho3+荧光粉

    Table  1.   Different concentrations of Bi3+ doped Lu2O3:Ho3+ phosphors

    sampleLu2O3 (%)Ho3+ (%)Bi3+ (%)
    198.5%1.5%0%
    297.5%0%1.5%
    397%1.5%1%
    496.5%1.5%1.5%
    598.5%1.5%2%
    下载: 导出CSV
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